A benzyl carbazate-based colorimetric chemosensor for relay detection of Cu2+ and S2− in near-perfect aqueous media

Soyoung Park; Donghwan Choe; Jae Jun Lee; Cheal Kim

doi:10.1016/j.molstruc.2021.130576

A benzyl carbazate-based colorimetric chemosensor for relay detection of Cu²⁺ and S²⁻ in near-perfect aqueous media

Soyoung Park
, Donghwan Choe
, Jae Jun Lee
, Cheal Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A benzyl carbazate-based colorimetric chemosensor HB (benzyl (E)-2-(2-hydroxy-3methoxy-5-nitrobenzylidene)hydrazine-1-carboxylate) was synthesized and used for relay detection of Cu²⁺ and S²⁻. HB can sense Cu²⁺ by the color variation from yellow to colorless and be used in real sample. HB-Cu²⁺ detected S²⁻ though demetallation with color variation form colorless to yellow. Detection limits of HB for Cu²⁺ and S²⁻ were calculated to be 0.20 and 0.60 μM which are greatly below WHO guidelines (31.4 and 14.8 μM). In addition, HB and HB-Cu²⁺ could detect Cu²⁺ and S²⁻, respectively, without any interference of other ions. The detection processes of HB to Cu²⁺ and S²⁻ were illustrated by ESI-MS, UV-visible spectroscopy and DFT calculation.

Original language	English
Article number	130576
Journal	Journal of Molecular Structure
Volume	1240
DOIs	https://doi.org/10.1016/j.molstruc.2021.130576
State	Published - 15 Sep 2021

Keywords

Chemosensor
Colorimetric
Cu
S
Water samples

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@article{ad60ae53781147b4954b931059a93929,

title = "A benzyl carbazate-based colorimetric chemosensor for relay detection of Cu2+ and S2− in near-perfect aqueous media",

abstract = "A benzyl carbazate-based colorimetric chemosensor HB (benzyl (E)-2-(2-hydroxy-3methoxy-5-nitrobenzylidene)hydrazine-1-carboxylate) was synthesized and used for relay detection of Cu2+ and S2−. HB can sense Cu2+ by the color variation from yellow to colorless and be used in real sample. HB-Cu2+ detected S2− though demetallation with color variation form colorless to yellow. Detection limits of HB for Cu2+ and S2− were calculated to be 0.20 and 0.60 μM which are greatly below WHO guidelines (31.4 and 14.8 μM). In addition, HB and HB-Cu2+ could detect Cu2+ and S2−, respectively, without any interference of other ions. The detection processes of HB to Cu2+ and S2− were illustrated by ESI-MS, UV-visible spectroscopy and DFT calculation.",

keywords = "Chemosensor, Colorimetric, Cu, S, Water samples",

author = "Soyoung Park and Donghwan Choe and Lee, \{Jae Jun\} and Cheal Kim",

note = "Publisher Copyright: {\textcopyright} 2021",

year = "2021",

month = sep,

day = "15",

doi = "10.1016/j.molstruc.2021.130576",

language = "English",

volume = "1240",

journal = "Journal of Molecular Structure",

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T1 - A benzyl carbazate-based colorimetric chemosensor for relay detection of Cu2+ and S2− in near-perfect aqueous media

AU - Park, Soyoung

AU - Choe, Donghwan

AU - Lee, Jae Jun

AU - Kim, Cheal

PY - 2021/9/15

Y1 - 2021/9/15

N2 - A benzyl carbazate-based colorimetric chemosensor HB (benzyl (E)-2-(2-hydroxy-3methoxy-5-nitrobenzylidene)hydrazine-1-carboxylate) was synthesized and used for relay detection of Cu2+ and S2−. HB can sense Cu2+ by the color variation from yellow to colorless and be used in real sample. HB-Cu2+ detected S2− though demetallation with color variation form colorless to yellow. Detection limits of HB for Cu2+ and S2− were calculated to be 0.20 and 0.60 μM which are greatly below WHO guidelines (31.4 and 14.8 μM). In addition, HB and HB-Cu2+ could detect Cu2+ and S2−, respectively, without any interference of other ions. The detection processes of HB to Cu2+ and S2− were illustrated by ESI-MS, UV-visible spectroscopy and DFT calculation.

AB - A benzyl carbazate-based colorimetric chemosensor HB (benzyl (E)-2-(2-hydroxy-3methoxy-5-nitrobenzylidene)hydrazine-1-carboxylate) was synthesized and used for relay detection of Cu2+ and S2−. HB can sense Cu2+ by the color variation from yellow to colorless and be used in real sample. HB-Cu2+ detected S2− though demetallation with color variation form colorless to yellow. Detection limits of HB for Cu2+ and S2− were calculated to be 0.20 and 0.60 μM which are greatly below WHO guidelines (31.4 and 14.8 μM). In addition, HB and HB-Cu2+ could detect Cu2+ and S2−, respectively, without any interference of other ions. The detection processes of HB to Cu2+ and S2− were illustrated by ESI-MS, UV-visible spectroscopy and DFT calculation.

KW - Chemosensor

KW - Colorimetric

KW - Cu

KW - S

KW - Water samples

UR - https://www.scopus.com/pages/publications/85106246568

U2 - 10.1016/j.molstruc.2021.130576

DO - 10.1016/j.molstruc.2021.130576

M3 - Article

AN - SCOPUS:85106246568

SN - 0022-2860

VL - 1240

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

M1 - 130576

ER -

A benzyl carbazate-based colorimetric chemosensor for relay detection of Cu²⁺ and S²⁻ in near-perfect aqueous media

Abstract

Keywords

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