A colorimetric F− chemosensor with high selectivity: experimental and theoretical studies

Hyoung Ha Ryu; Yun Jung Lee; So Eun Kim; Tae Geun Jo; Cheal Kim

doi:10.1007/s10847-016-0646-8

A colorimetric F⁻ chemosensor with high selectivity: experimental and theoretical studies

Hyoung Ha Ryu, Yun Jung Lee, So Eun Kim, Tae Geun Jo, Cheal Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Abstract: A new and simple colorimetric receptor 1, based on the combination of 2-amino-4-methylphenol moiety and julolidine moiety, has been designed and synthesized. 1 showed a selective colorimetric sensing ability toward F⁻ ion by changing color from yellow to orange, and could be utilized to monitor F⁻ without any inhibition by competitive anions such as CH₃COO⁻ and CN⁻. Based on Job plot, ESI-mass spectrometry and the ¹H NMR titration, the binding mode of 1 for F⁻ was proposed to be 1:1. Moreover, the sensing mechanism for F⁻ was theoretically supported by DFT and TD-DFT calculations. Graphical Abstract: [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	111-119
Number of pages	9
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	86
Issue number	1-2
DOIs	https://doi.org/10.1007/s10847-016-0646-8
State	Published - 1 Oct 2016

Keywords

Colorimetric chemosensor
Deprotonation
Fluoride
Theoretical calculations

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10.1007/s10847-016-0646-8

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title = "A colorimetric F− chemosensor with high selectivity: experimental and theoretical studies",

abstract = "Abstract: A new and simple colorimetric receptor 1, based on the combination of 2-amino-4-methylphenol moiety and julolidine moiety, has been designed and synthesized. 1 showed a selective colorimetric sensing ability toward F− ion by changing color from yellow to orange, and could be utilized to monitor F− without any inhibition by competitive anions such as CH3COO− and CN−. Based on Job plot, ESI-mass spectrometry and the 1H NMR titration, the binding mode of 1 for F− was proposed to be 1:1. Moreover, the sensing mechanism for F− was theoretically supported by DFT and TD-DFT calculations. Graphical Abstract: [Figure not available: see fulltext.]",

keywords = "Colorimetric chemosensor, Deprotonation, Fluoride, Theoretical calculations",

author = "Ryu, \{Hyoung Ha\} and Lee, \{Yun Jung\} and Kim, \{So Eun\} and Jo, \{Tae Geun\} and Cheal Kim",

note = "Publisher Copyright: {\textcopyright} 2016, Springer Science+Business Media Dordrecht.",

year = "2016",

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doi = "10.1007/s10847-016-0646-8",

language = "English",

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journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

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TY - JOUR

T1 - A colorimetric F− chemosensor with high selectivity

T2 - experimental and theoretical studies

AU - Ryu, Hyoung Ha

AU - Lee, Yun Jung

AU - Kim, So Eun

AU - Jo, Tae Geun

AU - Kim, Cheal

PY - 2016/10/1

Y1 - 2016/10/1

N2 - Abstract: A new and simple colorimetric receptor 1, based on the combination of 2-amino-4-methylphenol moiety and julolidine moiety, has been designed and synthesized. 1 showed a selective colorimetric sensing ability toward F− ion by changing color from yellow to orange, and could be utilized to monitor F− without any inhibition by competitive anions such as CH3COO− and CN−. Based on Job plot, ESI-mass spectrometry and the 1H NMR titration, the binding mode of 1 for F− was proposed to be 1:1. Moreover, the sensing mechanism for F− was theoretically supported by DFT and TD-DFT calculations. Graphical Abstract: [Figure not available: see fulltext.]

AB - Abstract: A new and simple colorimetric receptor 1, based on the combination of 2-amino-4-methylphenol moiety and julolidine moiety, has been designed and synthesized. 1 showed a selective colorimetric sensing ability toward F− ion by changing color from yellow to orange, and could be utilized to monitor F− without any inhibition by competitive anions such as CH3COO− and CN−. Based on Job plot, ESI-mass spectrometry and the 1H NMR titration, the binding mode of 1 for F− was proposed to be 1:1. Moreover, the sensing mechanism for F− was theoretically supported by DFT and TD-DFT calculations. Graphical Abstract: [Figure not available: see fulltext.]

KW - Colorimetric chemosensor

KW - Deprotonation

KW - Fluoride

KW - Theoretical calculations

UR - https://www.scopus.com/pages/publications/84984600012

U2 - 10.1007/s10847-016-0646-8

DO - 10.1007/s10847-016-0646-8

M3 - Article

AN - SCOPUS:84984600012

SN - 0923-0750

VL - 86

SP - 111

EP - 119

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 1-2

ER -

A colorimetric F⁻ chemosensor with high selectivity: experimental and theoretical studies

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Keywords

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