A new coumarin-based chromogenic chemosensor for the detection of dual analytes Al3+ and F-

Gyeong Jin Park; Hyun Yong Jo; Ka Young Ryu; Cheal Kim

doi:10.1039/c4ra11913d

A new coumarin-based chromogenic chemosensor for the detection of dual analytes Al³⁺ and F^-

Gyeong Jin Park, Hyun Yong Jo, Ka Young Ryu, Cheal Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

A multifunctional colorimetric receptor 1 (2-(3-nitro-2-oxo-2H-chromen-4-ylamino)-3-aminomaleonitrile) for the detection of both Al³⁺ and F^- has been developed. The receptor 1 showed a significant color change in the presence of Al³⁺ over most other competitive metal ions including Ga³⁺ and In³⁺ in aqueous solution. The selectivity mechanism of 1 for Al³⁺ might be attributed to the enhancement of the intramolecular charge transfer band. Interestingly, it could be recycled simply through treatment with an appropriate reagent such as ethylenediaminetetraacedtic acid. Moreover, 1 showed a highly selective colorimetric response to F^- due to the decrease in the intramolecular charge transfer band by a deprotonation process without any interference from other anions. Therefore, 1 can serve as a 'single sensor for dual targets'.

Original language	English
Pages (from-to)	63882-63890
Number of pages	9
Journal	RSC Advances
Volume	4
Issue number	109
DOIs	https://doi.org/10.1039/c4ra11913d
State	Published - 2014

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title = "A new coumarin-based chromogenic chemosensor for the detection of dual analytes Al3+ and F-",

abstract = "A multifunctional colorimetric receptor 1 (2-(3-nitro-2-oxo-2H-chromen-4-ylamino)-3-aminomaleonitrile) for the detection of both Al3+ and F- has been developed. The receptor 1 showed a significant color change in the presence of Al3+ over most other competitive metal ions including Ga3+ and In3+ in aqueous solution. The selectivity mechanism of 1 for Al3+ might be attributed to the enhancement of the intramolecular charge transfer band. Interestingly, it could be recycled simply through treatment with an appropriate reagent such as ethylenediaminetetraacedtic acid. Moreover, 1 showed a highly selective colorimetric response to F- due to the decrease in the intramolecular charge transfer band by a deprotonation process without any interference from other anions. Therefore, 1 can serve as a 'single sensor for dual targets'.",

author = "Park, \{Gyeong Jin\} and Jo, \{Hyun Yong\} and Ryu, \{Ka Young\} and Cheal Kim",

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doi = "10.1039/c4ra11913d",

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T1 - A new coumarin-based chromogenic chemosensor for the detection of dual analytes Al3+ and F-

AU - Park, Gyeong Jin

AU - Jo, Hyun Yong

AU - Ryu, Ka Young

AU - Kim, Cheal

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2014

Y1 - 2014

N2 - A multifunctional colorimetric receptor 1 (2-(3-nitro-2-oxo-2H-chromen-4-ylamino)-3-aminomaleonitrile) for the detection of both Al3+ and F- has been developed. The receptor 1 showed a significant color change in the presence of Al3+ over most other competitive metal ions including Ga3+ and In3+ in aqueous solution. The selectivity mechanism of 1 for Al3+ might be attributed to the enhancement of the intramolecular charge transfer band. Interestingly, it could be recycled simply through treatment with an appropriate reagent such as ethylenediaminetetraacedtic acid. Moreover, 1 showed a highly selective colorimetric response to F- due to the decrease in the intramolecular charge transfer band by a deprotonation process without any interference from other anions. Therefore, 1 can serve as a 'single sensor for dual targets'.

AB - A multifunctional colorimetric receptor 1 (2-(3-nitro-2-oxo-2H-chromen-4-ylamino)-3-aminomaleonitrile) for the detection of both Al3+ and F- has been developed. The receptor 1 showed a significant color change in the presence of Al3+ over most other competitive metal ions including Ga3+ and In3+ in aqueous solution. The selectivity mechanism of 1 for Al3+ might be attributed to the enhancement of the intramolecular charge transfer band. Interestingly, it could be recycled simply through treatment with an appropriate reagent such as ethylenediaminetetraacedtic acid. Moreover, 1 showed a highly selective colorimetric response to F- due to the decrease in the intramolecular charge transfer band by a deprotonation process without any interference from other anions. Therefore, 1 can serve as a 'single sensor for dual targets'.

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DO - 10.1039/c4ra11913d

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SN - 2046-2069

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JO - RSC Advances

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ER -

A new coumarin-based chromogenic chemosensor for the detection of dual analytes Al³⁺ and F^-

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