A nitrobenzodioxazole-based water-soluble chemosensor for colorimetric quantification of aqueous hypochlorite

Sungjin Moon; Dongkyun Gil; Cheal Kim

doi:10.1111/cote.12717

A nitrobenzodioxazole-based water-soluble chemosensor for colorimetric quantification of aqueous hypochlorite

Sungjin Moon, Dongkyun Gil, Cheal Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A nitrobenzoxadiazole (NBD)-based colorimetric chemosensor CNA (N,N,N-trimethyl-2-(2-(7-nitrobenzo[c][1,2,5]oxadiazol-4-yl)hydrazineyl)-2-oxoethan-1-aminium chloride) was synthesised. The sensor CNA can detect hypochlorite (ClO⁻) via colour variation of yellow to colourless. The detection limit for ClO⁻ by CNA was analysed to be 0.36 μM. Moreover, the naked-eye test strip was successfully applied for ClO⁻ detection. The probing mechanism of CNA to ClO⁻ was proposed to be a hydrolytic cleavage reaction of CNA by ClO⁻ and was demonstrated by electrospray ionisation mass spectrometry (ESI-MS), Fourier-transform infrared (FTIR), proton nuclear magnetic resonance (¹H NMR) analysis and density functional theory (DFT) calculations.

Original language	English
Pages (from-to)	412-421
Number of pages	10
Journal	Coloration Technology
Volume	140
Issue number	3
DOIs	https://doi.org/10.1111/cote.12717
State	Published - Jun 2024

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title = "A nitrobenzodioxazole-based water-soluble chemosensor for colorimetric quantification of aqueous hypochlorite",

abstract = "A nitrobenzoxadiazole (NBD)-based colorimetric chemosensor CNA (N,N,N-trimethyl-2-(2-(7-nitrobenzo[c][1,2,5]oxadiazol-4-yl)hydrazineyl)-2-oxoethan-1-aminium chloride) was synthesised. The sensor CNA can detect hypochlorite (ClO−) via colour variation of yellow to colourless. The detection limit for ClO− by CNA was analysed to be 0.36 μM. Moreover, the naked-eye test strip was successfully applied for ClO− detection. The probing mechanism of CNA to ClO− was proposed to be a hydrolytic cleavage reaction of CNA by ClO− and was demonstrated by electrospray ionisation mass spectrometry (ESI-MS), Fourier-transform infrared (FTIR), proton nuclear magnetic resonance (1H NMR) analysis and density functional theory (DFT) calculations.",

author = "Sungjin Moon and Dongkyun Gil and Cheal Kim",

note = "Publisher Copyright: {\textcopyright} 2023 Society of Dyers and Colourists.",

year = "2024",

month = jun,

doi = "10.1111/cote.12717",

language = "English",

volume = "140",

pages = "412--421",

journal = "Coloration Technology",

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T1 - A nitrobenzodioxazole-based water-soluble chemosensor for colorimetric quantification of aqueous hypochlorite

AU - Moon, Sungjin

AU - Gil, Dongkyun

AU - Kim, Cheal

PY - 2024/6

Y1 - 2024/6

N2 - A nitrobenzoxadiazole (NBD)-based colorimetric chemosensor CNA (N,N,N-trimethyl-2-(2-(7-nitrobenzo[c][1,2,5]oxadiazol-4-yl)hydrazineyl)-2-oxoethan-1-aminium chloride) was synthesised. The sensor CNA can detect hypochlorite (ClO−) via colour variation of yellow to colourless. The detection limit for ClO− by CNA was analysed to be 0.36 μM. Moreover, the naked-eye test strip was successfully applied for ClO− detection. The probing mechanism of CNA to ClO− was proposed to be a hydrolytic cleavage reaction of CNA by ClO− and was demonstrated by electrospray ionisation mass spectrometry (ESI-MS), Fourier-transform infrared (FTIR), proton nuclear magnetic resonance (1H NMR) analysis and density functional theory (DFT) calculations.

AB - A nitrobenzoxadiazole (NBD)-based colorimetric chemosensor CNA (N,N,N-trimethyl-2-(2-(7-nitrobenzo[c][1,2,5]oxadiazol-4-yl)hydrazineyl)-2-oxoethan-1-aminium chloride) was synthesised. The sensor CNA can detect hypochlorite (ClO−) via colour variation of yellow to colourless. The detection limit for ClO− by CNA was analysed to be 0.36 μM. Moreover, the naked-eye test strip was successfully applied for ClO− detection. The probing mechanism of CNA to ClO− was proposed to be a hydrolytic cleavage reaction of CNA by ClO− and was demonstrated by electrospray ionisation mass spectrometry (ESI-MS), Fourier-transform infrared (FTIR), proton nuclear magnetic resonance (1H NMR) analysis and density functional theory (DFT) calculations.

UR - https://www.scopus.com/pages/publications/85168890444

U2 - 10.1111/cote.12717

DO - 10.1111/cote.12717

M3 - Article

AN - SCOPUS:85168890444

SN - 1472-3581

VL - 140

SP - 412

EP - 421

JO - Coloration Technology

JF - Coloration Technology

IS - 3

ER -

A nitrobenzodioxazole-based water-soluble chemosensor for colorimetric quantification of aqueous hypochlorite

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