A simple colorimetric chemosensor bearing a carboxylic acid group with high selectivity for CN-

Gyeong Jin Park; Ye Won Choi; Dongkuk Lee; Cheal Kim

doi:10.1016/j.saa.2014.06.001

A simple colorimetric chemosensor bearing a carboxylic acid group with high selectivity for CN^-

Gyeong Jin Park
, Ye Won Choi
, Dongkuk Lee
, Cheal Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

A new simple 'naked eye' chemosensor 1 (sodium (E)-2-((2-(3-hydroxy-2- naphthoyl)hydrazono)methyl)benzoate) has been synthesized for detection of CN^- in a mixture of DMF/H₂O (9:1). The sensor 1 comprises of a naphthoic hydrazide as efficient hydrogen bonding donor group and a benzoic acid as the moiety with the water solubility. The receptor 1 showed high selectivity toward cyanide ions in a 1:1 stoichiometric manner, which induces a fast color change from colorless to yellow for CN^- over other anions. Therefore, receptor 1 could be useful for cyanide detection in aqueous environment, displaying a high distinguishable selectivity from hydrogen bonded anions and being clearly visible to the naked eye.

Original language	English
Pages (from-to)	771-775
Number of pages	5
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	132
DOIs	https://doi.org/10.1016/j.saa.2014.06.001
State	Published - 11 Nov 2014

Keywords

Carboxylic acid
Colorimetric
Cyanide
Deprotonation
Naphthoic hydrazide

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10.1016/j.saa.2014.06.001

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title = "A simple colorimetric chemosensor bearing a carboxylic acid group with high selectivity for CN-",

abstract = "A new simple 'naked eye' chemosensor 1 (sodium (E)-2-((2-(3-hydroxy-2- naphthoyl)hydrazono)methyl)benzoate) has been synthesized for detection of CN- in a mixture of DMF/H2O (9:1). The sensor 1 comprises of a naphthoic hydrazide as efficient hydrogen bonding donor group and a benzoic acid as the moiety with the water solubility. The receptor 1 showed high selectivity toward cyanide ions in a 1:1 stoichiometric manner, which induces a fast color change from colorless to yellow for CN- over other anions. Therefore, receptor 1 could be useful for cyanide detection in aqueous environment, displaying a high distinguishable selectivity from hydrogen bonded anions and being clearly visible to the naked eye.",

keywords = "Carboxylic acid, Colorimetric, Cyanide, Deprotonation, Naphthoic hydrazide",

author = "Park, \{Gyeong Jin\} and Choi, \{Ye Won\} and Dongkuk Lee and Cheal Kim",

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doi = "10.1016/j.saa.2014.06.001",

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journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

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T1 - A simple colorimetric chemosensor bearing a carboxylic acid group with high selectivity for CN-

AU - Park, Gyeong Jin

AU - Choi, Ye Won

AU - Lee, Dongkuk

AU - Kim, Cheal

PY - 2014/11/11

Y1 - 2014/11/11

N2 - A new simple 'naked eye' chemosensor 1 (sodium (E)-2-((2-(3-hydroxy-2- naphthoyl)hydrazono)methyl)benzoate) has been synthesized for detection of CN- in a mixture of DMF/H2O (9:1). The sensor 1 comprises of a naphthoic hydrazide as efficient hydrogen bonding donor group and a benzoic acid as the moiety with the water solubility. The receptor 1 showed high selectivity toward cyanide ions in a 1:1 stoichiometric manner, which induces a fast color change from colorless to yellow for CN- over other anions. Therefore, receptor 1 could be useful for cyanide detection in aqueous environment, displaying a high distinguishable selectivity from hydrogen bonded anions and being clearly visible to the naked eye.

AB - A new simple 'naked eye' chemosensor 1 (sodium (E)-2-((2-(3-hydroxy-2- naphthoyl)hydrazono)methyl)benzoate) has been synthesized for detection of CN- in a mixture of DMF/H2O (9:1). The sensor 1 comprises of a naphthoic hydrazide as efficient hydrogen bonding donor group and a benzoic acid as the moiety with the water solubility. The receptor 1 showed high selectivity toward cyanide ions in a 1:1 stoichiometric manner, which induces a fast color change from colorless to yellow for CN- over other anions. Therefore, receptor 1 could be useful for cyanide detection in aqueous environment, displaying a high distinguishable selectivity from hydrogen bonded anions and being clearly visible to the naked eye.

KW - Carboxylic acid

KW - Colorimetric

KW - Cyanide

KW - Deprotonation

KW - Naphthoic hydrazide

UR - https://www.scopus.com/pages/publications/84903214343

U2 - 10.1016/j.saa.2014.06.001

DO - 10.1016/j.saa.2014.06.001

M3 - Article

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AN - SCOPUS:84903214343

SN - 1386-1425

VL - 132

SP - 771

EP - 775

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

ER -

A simple colorimetric chemosensor bearing a carboxylic acid group with high selectivity for CN^-

Abstract

Keywords

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