A thiourea-naphthol based turn-on fluorescent sensor for detecting In3+ and its application

Su Chan Lee; Cheal Kim

doi:10.1016/j.inoche.2019.107752

A thiourea-naphthol based turn-on fluorescent sensor for detecting In³⁺ and its application

Su Chan Lee
, Cheal Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A highly selective thiourea-naphthol based fluorescent chemosensor SC ((E)-2-((8-hydroxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij] quinolin-9-yl) methylene)-N-(naphthalen-1-yl) hydrazine-1-carbothioamide) for sensing In³⁺ was developed. Sensor SC could detect In³⁺ by a fluorescent turn-on method in aqueous solution. The detection limit of SC for In³⁺ is calculated to be 9.62 μM. In addition, sensor SC successfully functioned as a visible fluorescent test kit for detecting In³⁺, and quantification of In³⁺ was also successful in real water samples with satisfactory recovery. Sensing mechanism of SC towards In³⁺ was identified by fluorescent and UV–vis titrations, FT-IR, NMR titration, ESI-MS and theoretical calculations.

Original language	English
Article number	107752
Journal	Inorganic Chemistry Communications
Volume	112
DOIs	https://doi.org/10.1016/j.inoche.2019.107752
State	Published - Feb 2020

Keywords

Fluorescent chemosenor
Indium
Naphthol
Test kit
Theoretical calculation
Thiourea

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10.1016/j.inoche.2019.107752

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title = "A thiourea-naphthol based turn-on fluorescent sensor for detecting In3+ and its application",

abstract = "A highly selective thiourea-naphthol based fluorescent chemosensor SC ((E)-2-((8-hydroxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij] quinolin-9-yl) methylene)-N-(naphthalen-1-yl) hydrazine-1-carbothioamide) for sensing In3+ was developed. Sensor SC could detect In3+ by a fluorescent turn-on method in aqueous solution. The detection limit of SC for In3+ is calculated to be 9.62 μM. In addition, sensor SC successfully functioned as a visible fluorescent test kit for detecting In3+, and quantification of In3+ was also successful in real water samples with satisfactory recovery. Sensing mechanism of SC towards In3+ was identified by fluorescent and UV–vis titrations, FT-IR, NMR titration, ESI-MS and theoretical calculations.",

keywords = "Fluorescent chemosenor, Indium, Naphthol, Test kit, Theoretical calculation, Thiourea",

author = "Lee, \{Su Chan\} and Cheal Kim",

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year = "2020",

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doi = "10.1016/j.inoche.2019.107752",

language = "English",

volume = "112",

journal = "Inorganic Chemistry Communications",

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T1 - A thiourea-naphthol based turn-on fluorescent sensor for detecting In3+ and its application

AU - Lee, Su Chan

AU - Kim, Cheal

PY - 2020/2

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N2 - A highly selective thiourea-naphthol based fluorescent chemosensor SC ((E)-2-((8-hydroxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij] quinolin-9-yl) methylene)-N-(naphthalen-1-yl) hydrazine-1-carbothioamide) for sensing In3+ was developed. Sensor SC could detect In3+ by a fluorescent turn-on method in aqueous solution. The detection limit of SC for In3+ is calculated to be 9.62 μM. In addition, sensor SC successfully functioned as a visible fluorescent test kit for detecting In3+, and quantification of In3+ was also successful in real water samples with satisfactory recovery. Sensing mechanism of SC towards In3+ was identified by fluorescent and UV–vis titrations, FT-IR, NMR titration, ESI-MS and theoretical calculations.

AB - A highly selective thiourea-naphthol based fluorescent chemosensor SC ((E)-2-((8-hydroxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij] quinolin-9-yl) methylene)-N-(naphthalen-1-yl) hydrazine-1-carbothioamide) for sensing In3+ was developed. Sensor SC could detect In3+ by a fluorescent turn-on method in aqueous solution. The detection limit of SC for In3+ is calculated to be 9.62 μM. In addition, sensor SC successfully functioned as a visible fluorescent test kit for detecting In3+, and quantification of In3+ was also successful in real water samples with satisfactory recovery. Sensing mechanism of SC towards In3+ was identified by fluorescent and UV–vis titrations, FT-IR, NMR titration, ESI-MS and theoretical calculations.

KW - Fluorescent chemosenor

KW - Indium

KW - Naphthol

KW - Test kit

KW - Theoretical calculation

KW - Thiourea

UR - https://www.scopus.com/pages/publications/85077322119

U2 - 10.1016/j.inoche.2019.107752

DO - 10.1016/j.inoche.2019.107752

M3 - Article

AN - SCOPUS:85077322119

SN - 1387-7003

VL - 112

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 107752

ER -

A thiourea-naphthol based turn-on fluorescent sensor for detecting In³⁺ and its application

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Keywords

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