TY - JOUR
T1 - Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa)
T2 - Novel heterogeneous catalytic activities
AU - Lee, Young Min
AU - Hong, Sung Jin
AU - Kim, Hee Jin
AU - Lee, Sun Hwa
AU - Kwak, Han
AU - Kim, Cheal
AU - Kim, Sung Jin
AU - Kim, Youngmee
PY - 2007/3
Y1 - 2007/3
N2 - The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.
AB - The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.
KW - 2,2′-Dipyridylamine ligand
KW - Heterogeneous catalyst
KW - Transesterification
KW - Znic(II) coordination polymer
UR - http://www.scopus.com/inward/record.url?scp=33846922603&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2006.11.001
DO - 10.1016/j.inoche.2006.11.001
M3 - Article
AN - SCOPUS:33846922603
SN - 1387-7003
VL - 10
SP - 287
EP - 291
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 3
ER -