Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities

Young Min Lee; Sung Jin Hong; Hee Jin Kim; Sun Hwa Lee; Han Kwak; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.inoche.2006.11.001

Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities

Young Min Lee
, Sung Jin Hong
, Hee Jin Kim
, Sun Hwa Lee
, Han Kwak
, Cheal Kim
, Sung Jin Kim
, Youngmee Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)
Ewha Womans University

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The reaction of ZnSO₄ with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.

Original language	English
Pages (from-to)	287-291
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2006.11.001
State	Published - Mar 2007

Keywords

2,2′-Dipyridylamine ligand
Heterogeneous catalyst
Transesterification
Znic(II) coordination polymer

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10.1016/j.inoche.2006.11.001

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title = "Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities",

abstract = "The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.",

keywords = "2,2′-Dipyridylamine ligand, Heterogeneous catalyst, Transesterification, Znic(II) coordination polymer",

author = "Lee, \{Young Min\} and Hong, \{Sung Jin\} and Kim, \{Hee Jin\} and Lee, \{Sun Hwa\} and Han Kwak and Cheal Kim and Kim, \{Sung Jin\} and Youngmee Kim",

year = "2007",

month = mar,

doi = "10.1016/j.inoche.2006.11.001",

language = "English",

volume = "10",

pages = "287--291",

journal = "Inorganic Chemistry Communications",

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T1 - Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa)

T2 - Novel heterogeneous catalytic activities

AU - Lee, Young Min

AU - Hong, Sung Jin

AU - Kim, Hee Jin

AU - Lee, Sun Hwa

AU - Kwak, Han

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

PY - 2007/3

Y1 - 2007/3

N2 - The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.

AB - The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.

KW - 2,2′-Dipyridylamine ligand

KW - Heterogeneous catalyst

KW - Transesterification

KW - Znic(II) coordination polymer

UR - https://www.scopus.com/pages/publications/33846922603

U2 - 10.1016/j.inoche.2006.11.001

DO - 10.1016/j.inoche.2006.11.001

M3 - Article

AN - SCOPUS:33846922603

SN - 1387-7003

VL - 10

SP - 287

EP - 291

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

ER -

Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities

Abstract

Keywords

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