TY - JOUR
T1 - Bis(di-2-pyridylmethane-diol-3 N,O,N′)nickel(II) dinitrate
AU - Yu, Seung Man
AU - Song, Young Joo
AU - Kim, Kang Chul
AU - Kim, Cheal
AU - Kim, Youngmee
PY - 2009
Y1 - 2009
N2 - The title compound, [Ni(C11H10N2O 2)2](NO3)2,consists of an Ni II atom coordinated by two tridentate chelating di-2-pyridylmethane- diol [(2py)2C(OH)2] ligands. The NiII atom is located on an inversion center. The geometry around the NiII atom is distorted octa-hedral. The gem-diol (2-py)2C(OH)2 ligand adopts the coordination mode 1:1:1. The Ni - N and Ni - O bond lengths are typical for high-spin NiII in an octa-hedral environment [Ni - N = 2.094 (2) and 2.124 (3) Å, and Ni - O = 2.108 (3) Å]. One of the hydr-oxy H atoms is split over two positions which both inter-act with the nitrate anion. The occurence of different O - H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.
AB - The title compound, [Ni(C11H10N2O 2)2](NO3)2,consists of an Ni II atom coordinated by two tridentate chelating di-2-pyridylmethane- diol [(2py)2C(OH)2] ligands. The NiII atom is located on an inversion center. The geometry around the NiII atom is distorted octa-hedral. The gem-diol (2-py)2C(OH)2 ligand adopts the coordination mode 1:1:1. The Ni - N and Ni - O bond lengths are typical for high-spin NiII in an octa-hedral environment [Ni - N = 2.094 (2) and 2.124 (3) Å, and Ni - O = 2.108 (3) Å]. One of the hydr-oxy H atoms is split over two positions which both inter-act with the nitrate anion. The occurence of different O - H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.
UR - https://www.scopus.com/pages/publications/67649884523
U2 - 10.1107/S1600536809018728
DO - 10.1107/S1600536809018728
M3 - Article
AN - SCOPUS:67649884523
SN - 1600-5368
VL - 65
SP - m678-m679
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 6
ER -