Bis(di-2-pyridylmethane-diol-3 N,O,N′)nickel(II) dinitrate

Seung Man Yu; Young Joo Song; Kang Chul Kim; Cheal Kim; Youngmee Kim

doi:10.1107/S1600536809018728

Bis(di-2-pyridylmethane-diol-³ N,O,N′)nickel(II) dinitrate

Seung Man Yu
, Young Joo Song
, Kang Chul Kim
, Cheal Kim
, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, [Ni(C₁₁H₁₀N₂O ₂)₂](NO₃)₂,consists of an Ni ^II atom coordinated by two tridentate chelating di-2-pyridylmethane- diol [(2py)₂C(OH)₂] ligands. The Ni^II atom is located on an inversion center. The geometry around the Ni^II atom is distorted octa-hedral. The gem-diol (2-py)₂C(OH)₂ ligand adopts the coordination mode ¹:¹:¹. The Ni - N and Ni - O bond lengths are typical for high-spin Ni^II in an octa-hedral environment [Ni - N = 2.094 (2) and 2.124 (3) Å, and Ni - O = 2.108 (3) Å]. One of the hydr-oxy H atoms is split over two positions which both inter-act with the nitrate anion. The occurence of different O - H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.

Original language	English
Pages (from-to)	m678-m679
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	6
DOIs	https://doi.org/10.1107/S1600536809018728
State	Published - 2009

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@article{8c5e3a320581405fab30f2d8a3d0b11b,

title = "Bis(di-2-pyridylmethane-diol-3 N,O,N′)nickel(II) dinitrate",

abstract = "The title compound, [Ni(C11H10N2O 2)2](NO3)2,consists of an Ni II atom coordinated by two tridentate chelating di-2-pyridylmethane- diol [(2py)2C(OH)2] ligands. The NiII atom is located on an inversion center. The geometry around the NiII atom is distorted octa-hedral. The gem-diol (2-py)2C(OH)2 ligand adopts the coordination mode 1:1:1. The Ni - N and Ni - O bond lengths are typical for high-spin NiII in an octa-hedral environment [Ni - N = 2.094 (2) and 2.124 (3) {\AA}, and Ni - O = 2.108 (3) {\AA}]. One of the hydr-oxy H atoms is split over two positions which both inter-act with the nitrate anion. The occurence of different O - H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.",

author = "Yu, \{Seung Man\} and Song, \{Young Joo\} and Kim, \{Kang Chul\} and Cheal Kim and Youngmee Kim",

year = "2009",

doi = "10.1107/S1600536809018728",

language = "English",

volume = "65",

pages = "m678--m679",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "6",

}

TY - JOUR

T1 - Bis(di-2-pyridylmethane-diol-3 N,O,N′)nickel(II) dinitrate

AU - Yu, Seung Man

AU - Song, Young Joo

AU - Kim, Kang Chul

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2009

Y1 - 2009

N2 - The title compound, [Ni(C11H10N2O 2)2](NO3)2,consists of an Ni II atom coordinated by two tridentate chelating di-2-pyridylmethane- diol [(2py)2C(OH)2] ligands. The NiII atom is located on an inversion center. The geometry around the NiII atom is distorted octa-hedral. The gem-diol (2-py)2C(OH)2 ligand adopts the coordination mode 1:1:1. The Ni - N and Ni - O bond lengths are typical for high-spin NiII in an octa-hedral environment [Ni - N = 2.094 (2) and 2.124 (3) Å, and Ni - O = 2.108 (3) Å]. One of the hydr-oxy H atoms is split over two positions which both inter-act with the nitrate anion. The occurence of different O - H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.

AB - The title compound, [Ni(C11H10N2O 2)2](NO3)2,consists of an Ni II atom coordinated by two tridentate chelating di-2-pyridylmethane- diol [(2py)2C(OH)2] ligands. The NiII atom is located on an inversion center. The geometry around the NiII atom is distorted octa-hedral. The gem-diol (2-py)2C(OH)2 ligand adopts the coordination mode 1:1:1. The Ni - N and Ni - O bond lengths are typical for high-spin NiII in an octa-hedral environment [Ni - N = 2.094 (2) and 2.124 (3) Å, and Ni - O = 2.108 (3) Å]. One of the hydr-oxy H atoms is split over two positions which both inter-act with the nitrate anion. The occurence of different O - H⋯O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.

UR - https://www.scopus.com/pages/publications/67649884523

U2 - 10.1107/S1600536809018728

DO - 10.1107/S1600536809018728

M3 - Article

AN - SCOPUS:67649884523

SN - 1600-5368

VL - 65

SP - m678-m679

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

Bis(di-2-pyridylmethane-diol-³ N,O,N′)nickel(II) dinitrate

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