TY - JOUR
T1 - Catena-Poly[[bis-(2,4-dichlorobenzoato)bis-(methanol-kO)cobalt(II)] -μ- 4,4′-bipyridine-k2 N:N′]
AU - Hyun, Min Young
AU - Kim, Pan Gi
AU - Kim, Cheal
AU - Kim, Youngmee
PY - 2011/12
Y1 - 2011/12
N2 - In the title compound, [Co(C7H3Cl2O 2)2(C10H8N2)(CH 3OH)2] n , the CoII ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO4N 2 environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the CoII ions, forming chains extending along [010]. An intra-chain O-H⋯O hydrogen bond is observed.
AB - In the title compound, [Co(C7H3Cl2O 2)2(C10H8N2)(CH 3OH)2] n , the CoII ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO4N 2 environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the CoII ions, forming chains extending along [010]. An intra-chain O-H⋯O hydrogen bond is observed.
KW - data-to-parameter ratio = 15.2
KW - mean σ(C-C) = 0.003 Å
KW - R factor = 0.035
KW - single-crystal X-ray study
KW - T = 288 K
KW - wR factor = 0.092
UR - http://www.scopus.com/inward/record.url?scp=83155183177&partnerID=8YFLogxK
U2 - 10.1107/S1600536811046149
DO - 10.1107/S1600536811046149
M3 - Article
AN - SCOPUS:83155183177
SN - 1600-5368
VL - 67
SP - m1705
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 12
ER -