Catena-Poly[[bis-(2,4-dichlorobenzoato)bis-(methanol-kO)cobalt(II)] -μ- 4,4′-bipyridine-k2 N:N′]

Min Young Hyun; Pan Gi Kim; Cheal Kim; Youngmee Kim

doi:10.1107/S1600536811046149

Catena-Poly[[bis-(2,4-dichlorobenzoato)bis-(methanol-kO)cobalt(II)] -μ- 4,4′-bipyridine-k² N:N′]

Min Young Hyun
, Pan Gi Kim
, Cheal Kim
, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Co(C₇H₃Cl₂O ₂)₂(C₁₀H₈N₂)(CH ₃OH)₂] n , the Co^II ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO₄N ₂ environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the Co^II ions, forming chains extending along [010]. An intra-chain O-H⋯O hydrogen bond is observed.

Original language	English
Pages (from-to)	m1705
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811046149
State	Published - Dec 2011

Keywords

R factor = 0.035
T = 288 K
data-to-parameter ratio = 15.2
mean σ(C-C) = 0.003 Å
single-crystal X-ray study
wR factor = 0.092

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@article{b962e95801ac4b1b9e470cd1b5550ce6,

title = "Catena-Poly[[bis-(2,4-dichlorobenzoato)bis-(methanol-kO)cobalt(II)] -μ- 4,4′-bipyridine-k2 N:N′]",

abstract = "In the title compound, [Co(C7H3Cl2O 2)2(C10H8N2)(CH 3OH)2] n , the CoII ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO4N 2 environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the CoII ions, forming chains extending along [010]. An intra-chain O-H⋯O hydrogen bond is observed.",

keywords = "R factor = 0.035, T = 288 K, data-to-parameter ratio = 15.2, mean σ(C-C) = 0.003 {\AA}, single-crystal X-ray study, wR factor = 0.092",

author = "Hyun, \{Min Young\} and Kim, \{Pan Gi\} and Cheal Kim and Youngmee Kim",

year = "2011",

month = dec,

doi = "10.1107/S1600536811046149",

language = "English",

volume = "67",

pages = "m1705",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - Catena-Poly[[bis-(2,4-dichlorobenzoato)bis-(methanol-kO)cobalt(II)] -μ- 4,4′-bipyridine-k2 N:N′]

AU - Hyun, Min Young

AU - Kim, Pan Gi

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2011/12

Y1 - 2011/12

N2 - In the title compound, [Co(C7H3Cl2O 2)2(C10H8N2)(CH 3OH)2] n , the CoII ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO4N 2 environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the CoII ions, forming chains extending along [010]. An intra-chain O-H⋯O hydrogen bond is observed.

AB - In the title compound, [Co(C7H3Cl2O 2)2(C10H8N2)(CH 3OH)2] n , the CoII ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO4N 2 environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the CoII ions, forming chains extending along [010]. An intra-chain O-H⋯O hydrogen bond is observed.

KW - R factor = 0.035

KW - T = 288 K

KW - data-to-parameter ratio = 15.2

KW - mean σ(C-C) = 0.003 Å

KW - single-crystal X-ray study

KW - wR factor = 0.092

UR - https://www.scopus.com/pages/publications/83155183177

U2 - 10.1107/S1600536811046149

DO - 10.1107/S1600536811046149

M3 - Article

AN - SCOPUS:83155183177

SN - 1600-5368

VL - 67

SP - m1705

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Catena-Poly[[bis-(2,4-dichlorobenzoato)bis-(methanol-kO)cobalt(II)] -μ- 4,4′-bipyridine-k² N:N′]

Abstract

Keywords

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