Catena-Poly[[tetraaqua[trans-1,2-bis(4-pyridyl)ethene-K2N: N′]nickel(II)]dinitrate]

Min Young Hyun; Pan Gi Kim; Cheal Kim; Youngmee Kim

doi:10.1107/S1600536811007021

Catena-Poly[[tetraaqua[trans-1,2-bis(4-pyridyl)ethene-K₂N: N′]nickel(II)]dinitrate]

Min Young Hyun
, Pan Gi Kim
, Cheal Kim
, Youngmee Kim

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)
Kyungpook National University
Ewha Womans University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In the title compound, {[Ni(C₁₂H₁₀N ₂)(H₂O)₄](NO₃)₂} n , the Ni^II ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis-(4-pyrid-yl)ethene ligands, which also have crystallographic inversion symmetry. These ligands bridge the Ni ^II complex units, forming chains extending along the [110] and [ 10] directions. The nitrate counter-anions stabilize the crystal structure through water-nitrate O - H⋯O hydrogen bonds.

Original language	English
Pages (from-to)	m390
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	4
DOIs	https://doi.org/10.1107/S1600536811007021
State	Published - Apr 2011

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@article{d4d3970741004a6e95236ec5b74ad93c,

title = "Catena-Poly[[tetraaqua[trans-1,2-bis(4-pyridyl)ethene-K2N: N′]nickel(II)]dinitrate]",

abstract = "In the title compound, \{[Ni(C12H10N 2)(H2O)4](NO3)2\} n , the NiII ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis-(4-pyrid-yl)ethene ligands, which also have crystallographic inversion symmetry. These ligands bridge the Ni II complex units, forming chains extending along the [110] and [ 10] directions. The nitrate counter-anions stabilize the crystal structure through water-nitrate O - H⋯O hydrogen bonds.",

author = "Hyun, \{Min Young\} and Kim, \{Pan Gi\} and Cheal Kim and Youngmee Kim",

year = "2011",

month = apr,

doi = "10.1107/S1600536811007021",

language = "English",

volume = "67",

pages = "m390",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

}

TY - JOUR

T1 - Catena-Poly[[tetraaqua[trans-1,2-bis(4-pyridyl)ethene-K2N

T2 - N′]nickel(II)]dinitrate]

AU - Hyun, Min Young

AU - Kim, Pan Gi

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2011/4

Y1 - 2011/4

N2 - In the title compound, {[Ni(C12H10N 2)(H2O)4](NO3)2} n , the NiII ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis-(4-pyrid-yl)ethene ligands, which also have crystallographic inversion symmetry. These ligands bridge the Ni II complex units, forming chains extending along the [110] and [ 10] directions. The nitrate counter-anions stabilize the crystal structure through water-nitrate O - H⋯O hydrogen bonds.

AB - In the title compound, {[Ni(C12H10N 2)(H2O)4](NO3)2} n , the NiII ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis-(4-pyrid-yl)ethene ligands, which also have crystallographic inversion symmetry. These ligands bridge the Ni II complex units, forming chains extending along the [110] and [ 10] directions. The nitrate counter-anions stabilize the crystal structure through water-nitrate O - H⋯O hydrogen bonds.

UR - https://www.scopus.com/pages/publications/79953798035

U2 - 10.1107/S1600536811007021

DO - 10.1107/S1600536811007021

M3 - Article

AN - SCOPUS:79953798035

SN - 1600-5368

VL - 67

SP - m390

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Catena-Poly[[tetraaqua[trans-1,2-bis(4-pyridyl)ethene-K₂N: N′]nickel(II)]dinitrate]

Abstract

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