TY - JOUR
T1 - CdII MOFs constructed using succinate and bipyridyl ligands
T2 - Photoluminescence and heterogeneous catalytic activity
AU - Lee, Myoung Mi
AU - Kim, Ha Yeong
AU - Hwang, In Hong
AU - Bae, Jeong Mi
AU - Kim, Cheal
AU - Yo, Chul Hyun
AU - Kim, Youngmee
AU - Kim, Sung Jin
PY - 2014/6/20
Y1 - 2014/6/20
N2 - Four CdII MOFs, [Cd2(μ-succinate) 2(H2O)2]·H2O (1A), [Cd 2(μ-succinate)2(μ-4,4′-bpy) 2]·H2O (1B), [{Cd2(μ-succinate) 2}(μ-bpa)2{Cd(H2O)2}(NO 3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp) 2]·2H2O (3), with various bipyridyl ligands (4,4′-bipyridine (4,4′-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.
AB - Four CdII MOFs, [Cd2(μ-succinate) 2(H2O)2]·H2O (1A), [Cd 2(μ-succinate)2(μ-4,4′-bpy) 2]·H2O (1B), [{Cd2(μ-succinate) 2}(μ-bpa)2{Cd(H2O)2}(NO 3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp) 2]·2H2O (3), with various bipyridyl ligands (4,4′-bipyridine (4,4′-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.
KW - Heterogeneous catalysts
KW - Photoluminescence
KW - Succinate
KW - Transesterification
UR - https://www.scopus.com/pages/publications/84902682765
U2 - 10.5012/bkcs.2014.35.6.1777
DO - 10.5012/bkcs.2014.35.6.1777
M3 - Article
AN - SCOPUS:84902682765
SN - 0253-2964
VL - 35
SP - 1777
EP - 1783
JO - Bulletin of the Korean Chemical Society
JF - Bulletin of the Korean Chemical Society
IS - 6
ER -