Construction of an interpenetrated 3-D network by [2 + 2] cycloaddition of Zn(ClO4)2 and 1,2-trans-(4-pyridyl)ethene: Counter anion effects

Jun Yong Lee; Sung Jin Hong; Cheal Kim; Youngmee Kim

doi:10.1039/b511520e

Construction of an interpenetrated 3-D network by [2 + 2] cycloaddition of Zn(ClO₄)₂ and 1,2-trans-(4-pyridyl)ethene: Counter anion effects

Jun Yong Lee, Sung Jin Hong, Cheal Kim, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The construction of an interpenetrated metal-organic polymer was studied. The reactions of zinc salts with 1,2-trans-(4-pyridyl)ethene were also investigated. A coordination-driven self-assembly directing a light-induced [ 2 + 2] cyclodimerization in solution was discussed. It is observed that the counter anions appear to be the driving force for organizing the olefinic double bonds to undergo [2 + 2] photodimerization.

Original language	English
Pages (from-to)	3716-3718
Number of pages	3
Journal	Dalton Transactions
Issue number	23
DOIs	https://doi.org/10.1039/b511520e
State	Published - 7 Dec 2005

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title = "Construction of an interpenetrated 3-D network by [2 + 2] cycloaddition of Zn(ClO4)2 and 1,2-trans-(4-pyridyl)ethene: Counter anion effects",

abstract = "The construction of an interpenetrated metal-organic polymer was studied. The reactions of zinc salts with 1,2-trans-(4-pyridyl)ethene were also investigated. A coordination-driven self-assembly directing a light-induced [ 2 + 2] cyclodimerization in solution was discussed. It is observed that the counter anions appear to be the driving force for organizing the olefinic double bonds to undergo [2 + 2] photodimerization.",

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T2 - Counter anion effects

AU - Lee, Jun Yong

AU - Hong, Sung Jin

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2005/12/7

Y1 - 2005/12/7

N2 - The construction of an interpenetrated metal-organic polymer was studied. The reactions of zinc salts with 1,2-trans-(4-pyridyl)ethene were also investigated. A coordination-driven self-assembly directing a light-induced [ 2 + 2] cyclodimerization in solution was discussed. It is observed that the counter anions appear to be the driving force for organizing the olefinic double bonds to undergo [2 + 2] photodimerization.

AB - The construction of an interpenetrated metal-organic polymer was studied. The reactions of zinc salts with 1,2-trans-(4-pyridyl)ethene were also investigated. A coordination-driven self-assembly directing a light-induced [ 2 + 2] cyclodimerization in solution was discussed. It is observed that the counter anions appear to be the driving force for organizing the olefinic double bonds to undergo [2 + 2] photodimerization.

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DO - 10.1039/b511520e

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ER -

Construction of an interpenetrated 3-D network by [2 + 2] cycloaddition of Zn(ClO₄)₂ and 1,2-trans-(4-pyridyl)ethene: Counter anion effects

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