Covalent organic polymer functionalization of activated carbon surfaces through acyl chloride for environmental clean-up

Nanoporous networks of covalent organic polymers (COPs) are successfully grafted on the surfaces of activated carbons, through a series of surface modification techniques, including acyl chloride formation by thionyl chloride. Hybrid composites of activated carbon functionalized with COPs exhibit a core-shell formation of COP material grafted to the outer layers of activated carbon. This general method brings features of both COPs and porous carbons together for target-specific environmental remediation applications, which was corroborated with successful adsorption tests for organic dyes and metals.