Crystal structure of [(1,2-bis(2-pyridine-2-carboxamido)-4,5- dimethylbenzene) (dipyridine)]cobalt(III) Perchlorate

Yeong Joon Kim; Cheal Kim; Youngmee Kim

doi:10.2116/analscix.21.x39

Crystal structure of [(1,2-bis(2-pyridine-2-carboxamido)-4,5- dimethylbenzene) (dipyridine)]cobalt(III) Perchlorate

Yeong Joon Kim, Cheal Kim, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Comment/debate

2 Scopus citations

Abstract

The structure of Co(III) complex containing a tetradentate Me₂bpb²- ligand and two pyridne ligands was determined by the X-ray diffraction method. Four N atoms of the 1,2-bis(pyridine-2-carboxamido)-4,5-dimethylbenzene (Me₂bpb²-) ligand and two pyridine ligands are coordinated to the Co(III) atom with an N(py)-Co-N(py) angle of 175.97(19)^o. The coordination geometry of the Co atom is octahedral(O_h) with six nitrogen atoms: four from a Me₂bpb²- ligand and two from pyridine ligands. 2005

Original language	English
Pages (from-to)	x39-x40
Journal	Analytical Sciences: X-ray Structure Analysis Online
Volume	21
Issue number	2
DOIs	https://doi.org/10.2116/analscix.21.x39
State	Published - Mar 2005

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title = "Crystal structure of [(1,2-bis(2-pyridine-2-carboxamido)-4,5- dimethylbenzene) (dipyridine)]cobalt(III) Perchlorate",

abstract = "The structure of Co(III) complex containing a tetradentate Me2bpb2- ligand and two pyridne ligands was determined by the X-ray diffraction method. Four N atoms of the 1,2-bis(pyridine-2-carboxamido)-4,5-dimethylbenzene (Me2bpb2-) ligand and two pyridine ligands are coordinated to the Co(III) atom with an N(py)-Co-N(py) angle of 175.97(19)o. The coordination geometry of the Co atom is octahedral(Oh) with six nitrogen atoms: four from a Me2bpb2- ligand and two from pyridine ligands. 2005",

author = "Kim, \{Yeong Joon\} and Cheal Kim and Youngmee Kim",

year = "2005",

month = mar,

doi = "10.2116/analscix.21.x39",

language = "English",

volume = "21",

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journal = "Analytical Sciences: X-ray Structure Analysis Online",

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T1 - Crystal structure of [(1,2-bis(2-pyridine-2-carboxamido)-4,5- dimethylbenzene) (dipyridine)]cobalt(III) Perchlorate

AU - Kim, Yeong Joon

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2005/3

Y1 - 2005/3

N2 - The structure of Co(III) complex containing a tetradentate Me2bpb2- ligand and two pyridne ligands was determined by the X-ray diffraction method. Four N atoms of the 1,2-bis(pyridine-2-carboxamido)-4,5-dimethylbenzene (Me2bpb2-) ligand and two pyridine ligands are coordinated to the Co(III) atom with an N(py)-Co-N(py) angle of 175.97(19)o. The coordination geometry of the Co atom is octahedral(Oh) with six nitrogen atoms: four from a Me2bpb2- ligand and two from pyridine ligands. 2005

AB - The structure of Co(III) complex containing a tetradentate Me2bpb2- ligand and two pyridne ligands was determined by the X-ray diffraction method. Four N atoms of the 1,2-bis(pyridine-2-carboxamido)-4,5-dimethylbenzene (Me2bpb2-) ligand and two pyridine ligands are coordinated to the Co(III) atom with an N(py)-Co-N(py) angle of 175.97(19)o. The coordination geometry of the Co atom is octahedral(Oh) with six nitrogen atoms: four from a Me2bpb2- ligand and two from pyridine ligands. 2005

UR - http://www.scopus.com/inward/record.url?scp=70450199128&partnerID=8YFLogxK

U2 - 10.2116/analscix.21.x39

DO - 10.2116/analscix.21.x39

M3 - Comment/debate

AN - SCOPUS:70450199128

SN - 1348-2238

VL - 21

SP - x39-x40

JO - Analytical Sciences: X-ray Structure Analysis Online

JF - Analytical Sciences: X-ray Structure Analysis Online

IS - 2

ER -

Crystal structure of [(1,2-bis(2-pyridine-2-carboxamido)-4,5- dimethylbenzene) (dipyridine)]cobalt(III) Perchlorate

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