Crystal structure of bis(tert-butanol)-α,β,γ,δ-tetraphenylporphyrinatomanganese(III) perchlorate

Cheal Kim; Jung Hee Han; Jun Yong Lee; Ji Young Ryu; Jin Soo Seo

doi:10.2116/analscix.20.x109

Crystal structure of bis(tert-butanol)-α,β,γ,δ-tetraphenylporphyrinatomanganese(III) perchlorate

Cheal Kim
, Jung Hee Han
, Jun Yong Lee
, Ji Young Ryu
, Jin Soo Seo

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)

Research output: Contribution to journal › Comment/debate

2 Scopus citations

Abstract

The structure of the title compound, [Mn(TPP)(t-BuOH)₂][ClO₄], has been determined by an X-ray diffraction method. Four N atoms of the porphyrin and two tert-butanols are coordinated to the Mn(III) ion. Long Mn-O(axial) distances of 2.299(4) and 2.287(4)Å and typical Mn-N(equatorial) distances of 1.988(4) - 1.995(4)Å lead to a tetragonal distortion. The O1-Mn-O2 bond angle is 175.06(14)°. 2004

Original language	English
Pages (from-to)	x109-x110
Journal	Analytical Sciences: X-ray Structure Analysis Online
Volume	20
Issue number	3
DOIs	https://doi.org/10.2116/analscix.20.x109
State	Published - 2004

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@article{260539758fc140b4a869dcde8cb56069,

title = "Crystal structure of bis(tert-butanol)-α,β,γ,δ-tetraphenylporphyrinatomanganese(III) perchlorate",

abstract = "The structure of the title compound, [Mn(TPP)(t-BuOH)2][ClO4], has been determined by an X-ray diffraction method. Four N atoms of the porphyrin and two tert-butanols are coordinated to the Mn(III) ion. Long Mn-O(axial) distances of 2.299(4) and 2.287(4){\AA} and typical Mn-N(equatorial) distances of 1.988(4) - 1.995(4){\AA} lead to a tetragonal distortion. The O1-Mn-O2 bond angle is 175.06(14)°. 2004",

author = "Cheal Kim and Han, \{Jung Hee\} and Lee, \{Jun Yong\} and Ryu, \{Ji Young\} and Seo, \{Jin Soo\}",

year = "2004",

doi = "10.2116/analscix.20.x109",

language = "English",

volume = "20",

pages = "x109--x110",

journal = "Analytical Sciences: X-ray Structure Analysis Online",

issn = "1348-2238",

number = "3",

}

TY - JOUR

T1 - Crystal structure of bis(tert-butanol)-α,β,γ,δ-tetraphenylporphyrinatomanganese(III) perchlorate

AU - Kim, Cheal

AU - Han, Jung Hee

AU - Lee, Jun Yong

AU - Ryu, Ji Young

AU - Seo, Jin Soo

PY - 2004

Y1 - 2004

N2 - The structure of the title compound, [Mn(TPP)(t-BuOH)2][ClO4], has been determined by an X-ray diffraction method. Four N atoms of the porphyrin and two tert-butanols are coordinated to the Mn(III) ion. Long Mn-O(axial) distances of 2.299(4) and 2.287(4)Å and typical Mn-N(equatorial) distances of 1.988(4) - 1.995(4)Å lead to a tetragonal distortion. The O1-Mn-O2 bond angle is 175.06(14)°. 2004

AB - The structure of the title compound, [Mn(TPP)(t-BuOH)2][ClO4], has been determined by an X-ray diffraction method. Four N atoms of the porphyrin and two tert-butanols are coordinated to the Mn(III) ion. Long Mn-O(axial) distances of 2.299(4) and 2.287(4)Å and typical Mn-N(equatorial) distances of 1.988(4) - 1.995(4)Å lead to a tetragonal distortion. The O1-Mn-O2 bond angle is 175.06(14)°. 2004

UR - https://www.scopus.com/pages/publications/33746380652

U2 - 10.2116/analscix.20.x109

DO - 10.2116/analscix.20.x109

M3 - Comment/debate

AN - SCOPUS:33746380652

SN - 1348-2238

VL - 20

SP - x109-x110

JO - Analytical Sciences: X-ray Structure Analysis Online

JF - Analytical Sciences: X-ray Structure Analysis Online

IS - 3

ER -

Crystal structure of bis(tert-butanol)-α,β,γ,δ-tetraphenylporphyrinatomanganese(III) perchlorate

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