Double hydroacylation reactions of acyclic and cyclic α,β- unsaturated aldehydes

Kyung Mi Cha; Hyejeong Lee; Jung Woo Park; Yura Lee; Eun Ae Jo; Chul Ho Jun

doi:10.1002/asia.201100298

Double hydroacylation reactions of acyclic and cyclic α,β- unsaturated aldehydes

Kyung Mi Cha
, Hyejeong Lee
, Jung Woo Park
, Yura Lee
, Eun Ae Jo
, Chul Ho Jun

Dept. of Fine Chemistry

Yonsei University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Double or quits? double hydroacylation reactions of acyclic and cyclic α,β-unsaturated aldehydes with olefins afford ketone and diketone products, respectively. Enantiomers are formed whose absolute configurations are controlled by the order of alkene addition.

Original language	English
Pages (from-to)	1926-1930
Number of pages	5
Journal	Chemistry - An Asian Journal
Volume	6
Issue number	8
DOIs	https://doi.org/10.1002/asia.201100298
State	Published - 1 Aug 2011

Keywords

acylation
C-H activation
cleavage reactions
homogeneous catalysis
transition metals

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10.1002/asia.201100298

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title = "Double hydroacylation reactions of acyclic and cyclic α,β- unsaturated aldehydes",

abstract = "Double or quits? double hydroacylation reactions of acyclic and cyclic α,β-unsaturated aldehydes with olefins afford ketone and diketone products, respectively. Enantiomers are formed whose absolute configurations are controlled by the order of alkene addition.",

keywords = "acylation, C-H activation, cleavage reactions, homogeneous catalysis, transition metals",

author = "Cha, \{Kyung Mi\} and Hyejeong Lee and Park, \{Jung Woo\} and Yura Lee and Jo, \{Eun Ae\} and Jun, \{Chul Ho\}",

year = "2011",

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doi = "10.1002/asia.201100298",

language = "English",

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journal = "Chemistry - An Asian Journal",

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AU - Cha, Kyung Mi

AU - Lee, Hyejeong

AU - Park, Jung Woo

AU - Lee, Yura

AU - Jo, Eun Ae

AU - Jun, Chul Ho

PY - 2011/8/1

Y1 - 2011/8/1

N2 - Double or quits? double hydroacylation reactions of acyclic and cyclic α,β-unsaturated aldehydes with olefins afford ketone and diketone products, respectively. Enantiomers are formed whose absolute configurations are controlled by the order of alkene addition.

AB - Double or quits? double hydroacylation reactions of acyclic and cyclic α,β-unsaturated aldehydes with olefins afford ketone and diketone products, respectively. Enantiomers are formed whose absolute configurations are controlled by the order of alkene addition.

KW - acylation

KW - C-H activation

KW - cleavage reactions

KW - homogeneous catalysis

KW - transition metals

UR - https://www.scopus.com/pages/publications/79961077763

U2 - 10.1002/asia.201100298

DO - 10.1002/asia.201100298

M3 - Article

C2 - 21688398

AN - SCOPUS:79961077763

SN - 1861-4728

VL - 6

SP - 1926

EP - 1930

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 8

ER -

Double hydroacylation reactions of acyclic and cyclic α,β- unsaturated aldehydes

Abstract

Keywords

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