Enhanced efficiency in GaInP/GaAs tandem solar cells using carbon doped GaAs in tunnel junction

Chang Zoo Kim, Hogyoung Kim, Keun Man Song, Dong Hwan Jun, Ho Kwan Kang, Wonkyu Park, Chul Gi Ko

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Carbon doping of GaAs using CBr4 (carbon tetrabromide) in metal-organic chemical vapor deposition (MOCVD) was investigated to obtain very high and sharp doping profiles required for tunnel junction in tandem solar cells. It was found that the hole concentration increased with decreasing growth temperature and V/III ratio. Hole doping profiles versus distance from the sample surface showed that the hole concentration near the surface was very low in comparison with that far below the surface. As a post-growth treatment, CBr4 was supplied during the cool down process and produced almost constant hole concentration of 1 × 1020 cm-3 regardless of the depth, when CBr4 flow rate was 9.53 μmol/min. Based on these results, solar cells were fabricated using both carbon (C) and zinc (Zn) as a p-type dopant. It was shown that C doping exhibits higher efficiency and lower series resistance than those of Zn doping in GaInP/GaAs tandem solar cells.

Original languageEnglish
Pages (from-to)677-681
Number of pages5
JournalMicroelectronic Engineering
Volume87
Issue number4
DOIs
StatePublished - Apr 2010

Keywords

  • Carbon doping
  • GaAs
  • MOCVD
  • Tandem solar cells

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