Exploration adsorption characteristics of zeolite 13X depending on humidity and flow rate in sorption thermal energy storage applications

Sorption thermal energy storage (STES) systems utilizing zeolite 13X present a promising solution to pressing global energy challenges. In this study, we explore the influence of absolute humidity and flow rate on the heat release process within a STES system, with a focus on local and overall performance considering temperature profile, degree of adsorption reaction, and average thermal power. A numerical model has been developed to investigate the adsorption kinetics of zeolite 13X and water, which is validated through experiments on pressure drop and transient temperature changes. In this study, we introduce P(%), a novel factor providing a holistic perspective of the adsorption process throughout the reactor. Through the analysis of P(%), we elucidate the link between the adsorption reaction, local heat transfer characteristics, and average thermal power within the reactor. Our findings reveal that increasing absolute humidity and flow rate accelerates the adsorption reaction of zeolite, leading to reduced discharge time. Our findings indicate that the adsorption reaction rate significantly decreases when P(%) approaches 95%. It is noteworthy, however, that the specific threshold of P(%) can vary based on the adsorbent type or reactor design. Despite this, P(%) can be utilized as a factor to establish the criteria for optimal control of STES. This research provides a guideline for optimum operational control and reactor design of STES systems.