Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

Jung Woo Park; Chul Ho Jun

doi:10.1021/ol701909e

Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

Jung Woo Park
, Chul Ho Jun

Dept. of Fine Chemistry

Yonsei University

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)₂RhCl]₂ and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.

Original language	English
Pages (from-to)	4073-4076
Number of pages	4
Journal	Organic Letters
Volume	9
Issue number	20
DOIs	https://doi.org/10.1021/ol701909e
State	Published - 27 Sep 2007

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title = "Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature",

abstract = "Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)2RhCl]2 and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.",

author = "Park, \{Jung Woo\} and Jun, \{Chul Ho\}",

year = "2007",

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doi = "10.1021/ol701909e",

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journal = "Organic Letters",

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T1 - Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

AU - Park, Jung Woo

AU - Jun, Chul Ho

PY - 2007/9/27

Y1 - 2007/9/27

N2 - Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)2RhCl]2 and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.

AB - Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)2RhCl]2 and HCl. In this reaction, a key intermediate is chlorosilane, generated from vinylsilane and HCl, which can be regenerated in the catalytic cycle. Various alcohols and vinylsilanes were applied to the preparation of silyl ether compounds with this catalyst system.

UR - https://www.scopus.com/pages/publications/35048885491

U2 - 10.1021/ol701909e

DO - 10.1021/ol701909e

M3 - Article

C2 - 17824712

AN - SCOPUS:35048885491

SN - 1523-7060

VL - 9

SP - 4073

EP - 4076

JO - Organic Letters

JF - Organic Letters

IS - 20

ER -

Highly efficient O-silylation of alcohol with vinylsilane using a Rh(l)/HCl catalyst at room temperature

Abstract

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