Kumada rearrangement of polydimethylsilane using a catalytic process

Younghee Kim; Dong Geun Shin; Hyung Rae Kim; Doug Young Han; Young Un Kang; Doh Hyung Riu

doi:10.4028/www.scientific.net/kem.317-318.85

Kumada rearrangement of polydimethylsilane using a catalytic process

Younghee Kim, Dong Geun Shin, Hyung Rae Kim, Doug Young Han, Young Un Kang, Doh Hyung Riu

Dept. of Materials Science & Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Polycarbosilane was synthesized from polydimethylsilane in the presence of ZSM-5 (Si/Al=30) as a catalyst at 350°C-400°C. Characterization of synthesized polycarbosilane was performed with ²⁹Si Solid NMR, FT-IR, and GPC analysis. Number average of molecular weight (M_n) of the polycarbosilane was ranged from 350 to 2340.

Original language	English
Pages (from-to)	85-88
Number of pages	4
Journal	Key Engineering Materials
Volume	317-318
DOIs	https://doi.org/10.4028/www.scientific.net/kem.317-318.85
State	Published - 2006

Keywords

Catalytic Process
Kumadar Rearrangement
Polycarbosilane
Polydimethylsilane

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title = "Kumada rearrangement of polydimethylsilane using a catalytic process",

abstract = "Polycarbosilane was synthesized from polydimethylsilane in the presence of ZSM-5 (Si/Al=30) as a catalyst at 350°C-400°C. Characterization of synthesized polycarbosilane was performed with 29Si Solid NMR, FT-IR, and GPC analysis. Number average of molecular weight (Mn) of the polycarbosilane was ranged from 350 to 2340.",

keywords = "Catalytic Process, Kumadar Rearrangement, Polycarbosilane, Polydimethylsilane",

author = "Younghee Kim and Shin, \{Dong Geun\} and Kim, \{Hyung Rae\} and Han, \{Doug Young\} and Kang, \{Young Un\} and Riu, \{Doh Hyung\}",

year = "2006",

doi = "10.4028/www.scientific.net/kem.317-318.85",

language = "English",

volume = "317-318",

pages = "85--88",

journal = "Key Engineering Materials",

issn = "1013-9826",

publisher = "Trans Tech Publications",

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TY - JOUR

T1 - Kumada rearrangement of polydimethylsilane using a catalytic process

AU - Kim, Younghee

AU - Shin, Dong Geun

AU - Kim, Hyung Rae

AU - Han, Doug Young

AU - Kang, Young Un

AU - Riu, Doh Hyung

PY - 2006

Y1 - 2006

N2 - Polycarbosilane was synthesized from polydimethylsilane in the presence of ZSM-5 (Si/Al=30) as a catalyst at 350°C-400°C. Characterization of synthesized polycarbosilane was performed with 29Si Solid NMR, FT-IR, and GPC analysis. Number average of molecular weight (Mn) of the polycarbosilane was ranged from 350 to 2340.

AB - Polycarbosilane was synthesized from polydimethylsilane in the presence of ZSM-5 (Si/Al=30) as a catalyst at 350°C-400°C. Characterization of synthesized polycarbosilane was performed with 29Si Solid NMR, FT-IR, and GPC analysis. Number average of molecular weight (Mn) of the polycarbosilane was ranged from 350 to 2340.

KW - Catalytic Process

KW - Kumadar Rearrangement

KW - Polycarbosilane

KW - Polydimethylsilane

UR - https://www.scopus.com/pages/publications/33746076666

U2 - 10.4028/www.scientific.net/kem.317-318.85

DO - 10.4028/www.scientific.net/kem.317-318.85

M3 - Article

AN - SCOPUS:33746076666

SN - 1013-9826

VL - 317-318

SP - 85

EP - 88

JO - Key Engineering Materials

JF - Key Engineering Materials

ER -

Kumada rearrangement of polydimethylsilane using a catalytic process

Abstract

Keywords

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