Linear Birefringence Behavior of K2ZnCl4 and [N(CH3)4]2ZnCl4 near the Normal-Incommensurate Phase Transition

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Abstract

The normal-incommensurate phase transition of K2ZnCl4 and [N(CH3)4]2ZnCl4 were studied by the linear birefringence method for the determining critical exponent, β. The critical linear birefringence behavior can well be described by standard 3-d XY model over the temperature range 10-3 < (Ti - T)/Ti < 10-2. The effect of symmetry breaking was not found in both K2ZnCl4 and [N(CH3)4]2ZnCl4. So we can determine the critical exponent β directly from linear birefringence by scaling analysis. As the temperature was decreased in K2ZnCl4 the critical linear birefringence behavior asymptotically approach to the prediction of classical mean field theory.

Original languageEnglish
Pages (from-to)3926-3930
Number of pages5
JournalJournal of the Physical Society of Japan
Volume65
Issue number12
DOIs
StatePublished - 1996

Keywords

  • Critical exponent, 3-d XY model
  • KZnCl
  • Linear birefringence
  • Normal-incommensurate phase transition
  • [N(CH)]ZnCl

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