Metal-silica spherical particles development by spray pyrolysis: Effect of metal species on surface area and toluene adsorption

Sangjin Han; Kye Sang Yoo; Daekeun Kim; Jinsoo Kim; Mohd Roslee Othman

doi:10.1016/j.jaap.2021.105049

Metal-silica spherical particles development by spray pyrolysis: Effect of metal species on surface area and toluene adsorption

Sangjin Han, Kye Sang Yoo, Daekeun Kim, Jinsoo Kim, Mohd Roslee Othman

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Zn-SiO₂ microspheres are an emerging material in the field of catalysis, separation, and sensor. In the development of Zn-SiO₂ microspheres by spray pyrolysis for a volatile organic component removal, the micro-spherical particles were observed to adsorb 3.4 mol kg⁻¹ of toluene at zinc concentration of 10 wt% in comparison with microspheres containing the same concentration of cobalt, nickel and iron species. Toluene gas with low inlet concentration of 0.1 % was used, indicating the high sensitivity of the Zn-SiO₂ microspheres. Zinc outperformed the other metal species due to the former's uniform spherical shape character and high affinity for toluene. The effect of surface area and pore characteristics of the microspheres on the toluene adsorption was also found to be profound.

Original language	English
Article number	105049
Journal	Journal of Analytical and Applied Pyrolysis
Volume	156
DOIs	https://doi.org/10.1016/j.jaap.2021.105049
State	Published - Jun 2021

Keywords

Mesoporous adsorbent
Spray pyrolysis
Toluene adsorption
VOC
Zinc-Silica microsphere

Access to Document

10.1016/j.jaap.2021.105049

Cite this

@article{162cb0c0e5e54e0fad5ac10bee13c1eb,

title = "Metal-silica spherical particles development by spray pyrolysis: Effect of metal species on surface area and toluene adsorption",

abstract = "Zn-SiO2 microspheres are an emerging material in the field of catalysis, separation, and sensor. In the development of Zn-SiO2 microspheres by spray pyrolysis for a volatile organic component removal, the micro-spherical particles were observed to adsorb 3.4 mol kg−1 of toluene at zinc concentration of 10 wt\% in comparison with microspheres containing the same concentration of cobalt, nickel and iron species. Toluene gas with low inlet concentration of 0.1 \% was used, indicating the high sensitivity of the Zn-SiO2 microspheres. Zinc outperformed the other metal species due to the former's uniform spherical shape character and high affinity for toluene. The effect of surface area and pore characteristics of the microspheres on the toluene adsorption was also found to be profound.",

keywords = "Mesoporous adsorbent, Spray pyrolysis, Toluene adsorption, VOC, Zinc-Silica microsphere",

author = "Sangjin Han and Yoo, \{Kye Sang\} and Daekeun Kim and Jinsoo Kim and Othman, \{Mohd Roslee\}",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2021",

month = jun,

doi = "10.1016/j.jaap.2021.105049",

language = "English",

volume = "156",

journal = "Journal of Analytical and Applied Pyrolysis",

issn = "0165-2370",

}

TY - JOUR

T1 - Metal-silica spherical particles development by spray pyrolysis

T2 - Effect of metal species on surface area and toluene adsorption

AU - Han, Sangjin

AU - Yoo, Kye Sang

AU - Kim, Daekeun

AU - Kim, Jinsoo

AU - Othman, Mohd Roslee

PY - 2021/6

Y1 - 2021/6

N2 - Zn-SiO2 microspheres are an emerging material in the field of catalysis, separation, and sensor. In the development of Zn-SiO2 microspheres by spray pyrolysis for a volatile organic component removal, the micro-spherical particles were observed to adsorb 3.4 mol kg−1 of toluene at zinc concentration of 10 wt% in comparison with microspheres containing the same concentration of cobalt, nickel and iron species. Toluene gas with low inlet concentration of 0.1 % was used, indicating the high sensitivity of the Zn-SiO2 microspheres. Zinc outperformed the other metal species due to the former's uniform spherical shape character and high affinity for toluene. The effect of surface area and pore characteristics of the microspheres on the toluene adsorption was also found to be profound.

AB - Zn-SiO2 microspheres are an emerging material in the field of catalysis, separation, and sensor. In the development of Zn-SiO2 microspheres by spray pyrolysis for a volatile organic component removal, the micro-spherical particles were observed to adsorb 3.4 mol kg−1 of toluene at zinc concentration of 10 wt% in comparison with microspheres containing the same concentration of cobalt, nickel and iron species. Toluene gas with low inlet concentration of 0.1 % was used, indicating the high sensitivity of the Zn-SiO2 microspheres. Zinc outperformed the other metal species due to the former's uniform spherical shape character and high affinity for toluene. The effect of surface area and pore characteristics of the microspheres on the toluene adsorption was also found to be profound.

KW - Mesoporous adsorbent

KW - Spray pyrolysis

KW - Toluene adsorption

KW - VOC

KW - Zinc-Silica microsphere

UR - http://www.scopus.com/inward/record.url?scp=85103544869&partnerID=8YFLogxK

U2 - 10.1016/j.jaap.2021.105049

DO - 10.1016/j.jaap.2021.105049

M3 - Article

AN - SCOPUS:85103544869

SN - 0165-2370

VL - 156

JO - Journal of Analytical and Applied Pyrolysis

JF - Journal of Analytical and Applied Pyrolysis

M1 - 105049

ER -

Metal-silica spherical particles development by spray pyrolysis: Effect of metal species on surface area and toluene adsorption

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this