MoO3/camphene 슬러리의 동결건조 및 수소환원에 의한 Mo 다공체 제조

Translated title of the contribution: Fabrication of Porous Mo by Freeze-Drying and Hydrogen Reduction of MoO3/Camphene Slurry

Research output: Contribution to journalArticlepeer-review

Abstract

In order to fabricate the porous Mo with controlled pore characteristics, unique processing by using MoO3powder as the source and camphene as the sublimable material is introduced. Camphene-based 15 vol% MoO3 slurries,prepared by milling at 50oC with a small amount of dispersant, were frozen at -25oC. Pores were generated subsequently by sublimation of the camphene during drying in air for 48 h. The green body was hydrogen-reduced at 750oC,and sintered at 1000-1100oC for 1 h. After heat treatment in hydrogen atmosphere, MoO3 powders were completely converted to metallic W without any reaction phases. The sintered samples showed large pores with the size of about 150μm which were aligned parallel to the camphene growth direction. Also, the internal wall of large pores and near bottom part of specimen had relatively small pores due to the difference in the camphene growth rate during freezing process.
The size of small pores was decreased with increase in sintering temperature, while that of large pores was unchanged. The results are strongly suggested that the porous metal with required pore characteristics can be successfully fabricated by freeze-drying process using metal oxide powders.
Translated title of the contributionFabrication of Porous Mo by Freeze-Drying and Hydrogen Reduction of MoO3/Camphene Slurry
Original languageKorean
Pages (from-to)446-450
Number of pages5
Journal한국분말야금학회지
Volume19
Issue number6
DOIs
StatePublished - Dec 2012

Fingerprint

Dive into the research topics of 'Fabrication of Porous Mo by Freeze-Drying and Hydrogen Reduction of MoO3/Camphene Slurry'. Together they form a unique fingerprint.

Cite this