Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity

Young Min Lee; Young Joo Song; Jung In Poong; Soo Hyun Kim; Hyo Geun Koo; Jung Ah Lee; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.inoche.2009.10.028

Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M₂M′(O₂CPh)₆](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity

Young Min Lee, Young Joo Song, Jung In Poong, Soo Hyun Kim, Hyo Geun Koo, Jung Ah Lee, Cheal Kim, Sung Jin Kim, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M₂M′(O₂CC₆H₅]_n(bpa)_n (bpa = 1,2-bis(4-pyridyl)ethane, M₂M′ = Zn₂Co (1), Zn₂Cd (2), and Co₂Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.

Original language	English
Pages (from-to)	101-104
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2009.10.028
State	Published - Jan 2010

Keywords

1,2-Bis(4-pyridyl)ethane
Heterometallic complex
One-dimensional chain
Transesterification

Access to Document

10.1016/j.inoche.2009.10.028

Cite this

Lee, Y. M., Song, Y. J., Poong, J. I., Kim, S. H., Koo, H. G., Lee, J. A., Kim, C., Kim, S. J., & Kim, Y. (2010). Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M₂M′(O₂CPh)₆](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity. Inorganic Chemistry Communications, 13(1), 101-104. https://doi.org/10.1016/j.inoche.2009.10.028

@article{1ab1ce65f62b44c2b69a86a51a308d46,

title = "Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity",

abstract = "Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M′(O2CC6H5]n(bpa)n (bpa = 1,2-bis(4-pyridyl)ethane, M2M′ = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.",

keywords = "1,2-Bis(4-pyridyl)ethane, Heterometallic complex, One-dimensional chain, Transesterification",

author = "Lee, \{Young Min\} and Song, \{Young Joo\} and Poong, \{Jung In\} and Kim, \{Soo Hyun\} and Koo, \{Hyo Geun\} and Lee, \{Jung Ah\} and Cheal Kim and Kim, \{Sung Jin\} and Youngmee Kim",

year = "2010",

month = jan,

doi = "10.1016/j.inoche.2009.10.028",

language = "English",

volume = "13",

pages = "101--104",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

number = "1",

}

Lee, YM, Song, YJ, Poong, JI, Kim, SH, Koo, HG, Lee, JA, Kim, C, Kim, SJ & Kim, Y 2010, 'Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M₂M′(O₂CPh)₆](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity', Inorganic Chemistry Communications, vol. 13, no. 1, pp. 101-104. https://doi.org/10.1016/j.inoche.2009.10.028

Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M₂M′(O₂CPh)₆](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity. / Lee, Young Min; Song, Young Joo; Poong, Jung In et al.
In: Inorganic Chemistry Communications, Vol. 13, No. 1, 01.2010, p. 101-104.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd)

T2 - Their catalytic activity

AU - Lee, Young Min

AU - Song, Young Joo

AU - Poong, Jung In

AU - Kim, Soo Hyun

AU - Koo, Hyo Geun

AU - Lee, Jung Ah

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

PY - 2010/1

Y1 - 2010/1

N2 - Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M′(O2CC6H5]n(bpa)n (bpa = 1,2-bis(4-pyridyl)ethane, M2M′ = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.

AB - Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M′(O2CC6H5]n(bpa)n (bpa = 1,2-bis(4-pyridyl)ethane, M2M′ = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.

KW - 1,2-Bis(4-pyridyl)ethane

KW - Heterometallic complex

KW - One-dimensional chain

KW - Transesterification

UR - http://www.scopus.com/inward/record.url?scp=72249101729&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2009.10.028

DO - 10.1016/j.inoche.2009.10.028

M3 - Article

AN - SCOPUS:72249101729

SN - 1387-7003

VL - 13

SP - 101

EP - 104

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M₂M′(O₂CPh)₆](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this