Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

Jung Hwan Lee; Hee Jin Kim; Yun Wee Choi; Young Min Lee; Byeong Kwon Park; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.poly.2006.11.020

Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

Jung Hwan Lee, Hee Jin Kim, Yun Wee Choi, Young Min Lee, Byeong Kwon Park, Cheal Kim, Sung Jin Kim, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me₂bpX^2- ligands (6Me₂bpX^2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.

Original language	English
Pages (from-to)	1388-1396
Number of pages	9
Journal	Polyhedron
Volume	26
Issue number	7
DOIs	https://doi.org/10.1016/j.poly.2006.11.020
State	Published - 1 May 2007

Keywords

Crystal structures
Non-classical hydrogen bonds
Palladium(II) complexes
Suzuki-Miyaura cross-coupling

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10.1016/j.poly.2006.11.020

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title = "Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex",

abstract = "New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.",

keywords = "Crystal structures, Non-classical hydrogen bonds, Palladium(II) complexes, Suzuki-Miyaura cross-coupling",

author = "Lee, \{Jung Hwan\} and Kim, \{Hee Jin\} and Choi, \{Yun Wee\} and Lee, \{Young Min\} and Park, \{Byeong Kwon\} and Cheal Kim and Kim, \{Sung Jin\} and Youngmee Kim",

year = "2007",

month = may,

day = "1",

doi = "10.1016/j.poly.2006.11.020",

language = "English",

volume = "26",

pages = "1388--1396",

journal = "Polyhedron",

issn = "0277-5387",

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TY - JOUR

T1 - Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl)

T2 - Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

AU - Lee, Jung Hwan

AU - Kim, Hee Jin

AU - Choi, Yun Wee

AU - Lee, Young Min

AU - Park, Byeong Kwon

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

PY - 2007/5/1

Y1 - 2007/5/1

N2 - New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.

AB - New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions.

KW - Crystal structures

KW - Non-classical hydrogen bonds

KW - Palladium(II) complexes

KW - Suzuki-Miyaura cross-coupling

UR - http://www.scopus.com/inward/record.url?scp=34147179972&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2006.11.020

DO - 10.1016/j.poly.2006.11.020

M3 - Article

AN - SCOPUS:34147179972

SN - 0277-5387

VL - 26

SP - 1388

EP - 1396

JO - Polyhedron

JF - Polyhedron

IS - 7

ER -

Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

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