TY - JOUR
T1 - Performance evaluations of carbonized low-density polyethylenes considered carbon supporter for electrodes of membraneless flow-type enzymatic biofuel cells
AU - Kim, Seongjun
AU - Ji, Jungyeon
AU - Lim, Hyeonsoo
AU - Shin, Mingyu
AU - Oh, Sung Tag
AU - Phae, Chae Gun
AU - Kwon, Yongchai
N1 - Publisher Copyright:
© 2023 Elsevier Ltd
PY - 2023/10
Y1 - 2023/10
N2 - Plastic products have many applications due to their low cost and simple production. However, since their remaining wastes can be a resource of environmental pollution, recycling of plastic waste is significant. In this study, for doing that, tertiary recycling of low-density polyethylenes (LDPEs) that are plastic waste is newly explored. With that, LDPEs are converted into useful carbonized LDPEs (C-LDPEs) used as Supporting material for electrodes of enzymatic biofuel cells (EBFCs) by stabilization and carbonization process. By recycling of LDPEs, their surface area increases, while desirable graphitic structure is produced. Glucose oxidase- and bilirubin oxidase-based catalytic structures are then loaded onto C-LDPEs to complete electrodes. After confirming excellence in their catalytic activity, the performance of membraneless flow-type EBFCs using C-LDPE based electrodes is measured. According to the evaluations, their open circuit voltage and maximum power density are 0.64 ± 0.03 V and 20.5 ± 1.3 μW cm-2.
AB - Plastic products have many applications due to their low cost and simple production. However, since their remaining wastes can be a resource of environmental pollution, recycling of plastic waste is significant. In this study, for doing that, tertiary recycling of low-density polyethylenes (LDPEs) that are plastic waste is newly explored. With that, LDPEs are converted into useful carbonized LDPEs (C-LDPEs) used as Supporting material for electrodes of enzymatic biofuel cells (EBFCs) by stabilization and carbonization process. By recycling of LDPEs, their surface area increases, while desirable graphitic structure is produced. Glucose oxidase- and bilirubin oxidase-based catalytic structures are then loaded onto C-LDPEs to complete electrodes. After confirming excellence in their catalytic activity, the performance of membraneless flow-type EBFCs using C-LDPE based electrodes is measured. According to the evaluations, their open circuit voltage and maximum power density are 0.64 ± 0.03 V and 20.5 ± 1.3 μW cm-2.
KW - Carbon supporter
KW - Enzymatic biofuel cell
KW - Low-density Polyethylene
KW - Plastic wastes
KW - Recycling
UR - http://www.scopus.com/inward/record.url?scp=85171839891&partnerID=8YFLogxK
U2 - 10.1016/j.jece.2023.111062
DO - 10.1016/j.jece.2023.111062
M3 - Article
AN - SCOPUS:85171839891
SN - 2213-3437
VL - 11
JO - Journal of Environmental Chemical Engineering
JF - Journal of Environmental Chemical Engineering
IS - 5
M1 - 111062
ER -