Potassium Boc-protected secondary aminomethyltrifluoroborates: Synthesis and Suzuki-Miyaura cross-coupling reactions

Gary A. Molander, Inji Shin

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

Seven potassium Boc-protected secondary aminomethyltrifluoroborates were prepared in a standardized two-step process. The Suzuki-Miyaura cross-coupling reaction was studied with this new class of nucleophiles, and a large variety of aryl and hetaryl chlorides provided the desired products in good to excellent yields, thereby allowing easy access to secondary aminomethyl substructures.

Original languageEnglish
Pages (from-to)4458-4461
Number of pages4
JournalOrganic Letters
Volume14
Issue number17
DOIs
StatePublished - 7 Sep 2012

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