Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

Jigyoung Yi; Hye Mi Ahn; Jong Ho Yoon; Cheal Kim; Suk Joong Lee

doi:10.1039/c8nj02214c

Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

Jigyoung Yi, Hye Mi Ahn, Jong Ho Yoon, Cheal Kim, Suk Joong Lee

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization of CuCl₂ gave POP-Cu(ii). This new heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation of the homogeneous catalyst was successfully inhibited by site isolation.

Original language	English
Pages (from-to)	14067-14070
Number of pages	4
Journal	New Journal of Chemistry
Volume	42
Issue number	17
DOIs	https://doi.org/10.1039/c8nj02214c
State	Published - 2018

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title = "Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation",

abstract = "A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization of CuCl2 gave POP-Cu(ii). This new heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation of the homogeneous catalyst was successfully inhibited by site isolation.",

author = "Jigyoung Yi and Ahn, \{Hye Mi\} and Yoon, \{Jong Ho\} and Cheal Kim and Lee, \{Suk Joong\}",

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T1 - Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

AU - Yi, Jigyoung

AU - Ahn, Hye Mi

AU - Yoon, Jong Ho

AU - Kim, Cheal

AU - Lee, Suk Joong

PY - 2018

Y1 - 2018

N2 - A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization of CuCl2 gave POP-Cu(ii). This new heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation of the homogeneous catalyst was successfully inhibited by site isolation.

AB - A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization of CuCl2 gave POP-Cu(ii). This new heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation of the homogeneous catalyst was successfully inhibited by site isolation.

UR - http://www.scopus.com/inward/record.url?scp=85051919339&partnerID=8YFLogxK

U2 - 10.1039/c8nj02214c

DO - 10.1039/c8nj02214c

M3 - Article

AN - SCOPUS:85051919339

SN - 1144-0546

VL - 42

SP - 14067

EP - 14070

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 17

ER -

Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

Abstract

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