Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence

Dong Su Kim; Jung Woo Park; Chul Ho Jun

doi:10.1039/c2cc36699a

Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)₂ oxidation and Rh(III)-catalyzed N-annulation sequence

Dong Su Kim
, Jung Woo Park
, Chul Ho Jun

Dept. of Fine Chemistry

Yonsei University

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.

Original language	English
Pages (from-to)	11334-11336
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	92
DOIs	https://doi.org/10.1039/c2cc36699a
State	Published - 24 Oct 2012

Access to Document

10.1039/c2cc36699a

Cite this

@article{b2e944526b2a445bbbc000370dbe7577,

title = "Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence",

abstract = "A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.",

author = "Kim, \{Dong Su\} and Park, \{Jung Woo\} and Jun, \{Chul Ho\}",

year = "2012",

month = oct,

day = "24",

doi = "10.1039/c2cc36699a",

language = "English",

volume = "48",

pages = "11334--11336",

journal = "Chemical Communications",

issn = "1359-7345",

number = "92",

}

TY - JOUR

T1 - Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence

AU - Kim, Dong Su

AU - Park, Jung Woo

AU - Jun, Chul Ho

PY - 2012/10/24

Y1 - 2012/10/24

N2 - A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.

AB - A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.

UR - https://www.scopus.com/pages/publications/84867940092

U2 - 10.1039/c2cc36699a

DO - 10.1039/c2cc36699a

M3 - Article

C2 - 23069867

AN - SCOPUS:84867940092

SN - 1359-7345

VL - 48

SP - 11334

EP - 11336

JO - Chemical Communications

JF - Chemical Communications

IS - 92

ER -

Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)₂ oxidation and Rh(III)-catalyzed N-annulation sequence

Abstract

Access to Document

Other files and links

Fingerprint

Cite this