Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

Jung Woo Park; Hoon Jo Chang; Chul Ho Jun

doi:10.2106/JBJS.E.00762

Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

Jung Woo Park
, Hoon Jo Chang
, Chul Ho Jun

Dept. of Fine Chemistry

Yonsei University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.

Original language	English
Pages (from-to)	771-775
Number of pages	5
Journal	Synlett
Issue number	5
DOIs	https://doi.org/10.2106/JBJS.E.00762
State	Published - 17 Mar 2006

Keywords

Alcohol
O-H bond cleavage
Silyl ether
Vinylsilane
Wilkinson's complex

Access to Document

10.2106/JBJS.E.00762

Cite this

@article{c79911c49cf044088ab53a50ab653cfa,

title = "Rh(I)-catalyzed O-silylation of alcohol with vinylsilane",

abstract = "Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.",

keywords = "Alcohol, O-H bond cleavage, Silyl ether, Vinylsilane, Wilkinson's complex",

author = "Park, \{Jung Woo\} and Chang, \{Hoon Jo\} and Jun, \{Chul Ho\}",

year = "2006",

month = mar,

day = "17",

doi = "10.2106/JBJS.E.00762",

language = "English",

pages = "771--775",

journal = "Synlett",

issn = "0936-5214",

number = "5",

}

TY - JOUR

T1 - Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

AU - Park, Jung Woo

AU - Chang, Hoon Jo

AU - Jun, Chul Ho

PY - 2006/3/17

Y1 - 2006/3/17

N2 - Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.

AB - Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.

KW - Alcohol

KW - O-H bond cleavage

KW - Silyl ether

KW - Vinylsilane

KW - Wilkinson's complex

UR - https://www.scopus.com/pages/publications/33645392240

U2 - 10.2106/JBJS.E.00762

DO - 10.2106/JBJS.E.00762

M3 - Article

AN - SCOPUS:33645392240

SN - 0936-5214

SP - 771

EP - 775

JO - Synlett

JF - Synlett

IS - 5

ER -

Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this