Sc(OTf)3-mediated silylation of hydroxy functional groups on a solid surface: A catalytic grafting method operating at room temperature

Ye Rim Yeon; Young Jun Park; Ji Sung Lee; Jung Woo Park; Sin Gun Kang; Chul Ho Jun

doi:10.1002/anie.200703112

Sc(OTf)₃-mediated silylation of hydroxy functional groups on a solid surface: A catalytic grafting method operating at room temperature

Ye Rim Yeon, Young Jun Park, Ji Sung Lee, Jung Woo Park, Sin Gun Kang, Chul Ho Jun

Dept. of Fine Chemistry

Yonsei University

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

(Chemical Equation Presented) Surface paradise: Facile catalytic post-grafting of the surface of glass or indium tin oxide (ITO, see picture) with a variety of functional groups has been achieved. Methallylsilanes serve as the grafting reagent and the surfaces show remarkable chemical stability.

Original language	English
Pages (from-to)	109-112
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	1
DOIs	https://doi.org/10.1002/anie.200703112
State	Published - 2008

Keywords

Glasses
Methallylsilane
Scandium
Silicon
Surface chemistry

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10.1002/anie.200703112

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title = "Sc(OTf)3-mediated silylation of hydroxy functional groups on a solid surface: A catalytic grafting method operating at room temperature",

abstract = "(Chemical Equation Presented) Surface paradise: Facile catalytic post-grafting of the surface of glass or indium tin oxide (ITO, see picture) with a variety of functional groups has been achieved. Methallylsilanes serve as the grafting reagent and the surfaces show remarkable chemical stability.",

keywords = "Glasses, Methallylsilane, Scandium, Silicon, Surface chemistry",

author = "Yeon, \{Ye Rim\} and Park, \{Young Jun\} and Lee, \{Ji Sung\} and Park, \{Jung Woo\} and Kang, \{Sin Gun\} and Jun, \{Chul Ho\}",

year = "2008",

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pages = "109--112",

journal = "Angewandte Chemie - International Edition",

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T2 - A catalytic grafting method operating at room temperature

AU - Yeon, Ye Rim

AU - Park, Young Jun

AU - Lee, Ji Sung

AU - Park, Jung Woo

AU - Kang, Sin Gun

AU - Jun, Chul Ho

PY - 2008

Y1 - 2008

N2 - (Chemical Equation Presented) Surface paradise: Facile catalytic post-grafting of the surface of glass or indium tin oxide (ITO, see picture) with a variety of functional groups has been achieved. Methallylsilanes serve as the grafting reagent and the surfaces show remarkable chemical stability.

AB - (Chemical Equation Presented) Surface paradise: Facile catalytic post-grafting of the surface of glass or indium tin oxide (ITO, see picture) with a variety of functional groups has been achieved. Methallylsilanes serve as the grafting reagent and the surfaces show remarkable chemical stability.

KW - Glasses

KW - Methallylsilane

KW - Scandium

KW - Silicon

KW - Surface chemistry

UR - https://www.scopus.com/pages/publications/37549012945

U2 - 10.1002/anie.200703112

DO - 10.1002/anie.200703112

M3 - Article

C2 - 17992671

AN - SCOPUS:37549012945

SN - 1433-7851

VL - 47

SP - 109

EP - 112

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 1

ER -

Sc(OTf)₃-mediated silylation of hydroxy functional groups on a solid surface: A catalytic grafting method operating at room temperature

Abstract

Keywords

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