Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid

Wonwoo Nam; Ju Yeon Ryu; Inwoo Kim; Cheal Kim

doi:10.1016/S0040-4039(02)01060-2

Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid

Wonwoo Nam, Ju Yeon Ryu, Inwoo Kim, Cheal Kim

Dept. of Fine Chemistry

Ewha Womans University

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Simple metal (M=Mn, Fe, Co) perchlorates associated with m-chloroperbenzoic acid are able to conduct stereoselective alkane hydroxylations via a mechanism involving metal-based oxidants; the catalytic activity of the metal salts is in the order of Co(ClO₄)₂>Mn(ClO₄)₂>Fe (ClO₄)₂.

Original language	English
Pages (from-to)	5487-5490
Number of pages	4
Journal	Tetrahedron Letters
Volume	43
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(02)01060-2
State	Published - 29 Jul 2002

Keywords

Alkane hydroxylation
Biomimetic
Catalysis
m-chloroperbenzoic acid
Metal perchlorate
Monooxygenases

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10.1016/S0040-4039(02)01060-2

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title = "Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid",

abstract = "Simple metal (M=Mn, Fe, Co) perchlorates associated with m-chloroperbenzoic acid are able to conduct stereoselective alkane hydroxylations via a mechanism involving metal-based oxidants; the catalytic activity of the metal salts is in the order of Co(ClO4)2>Mn(ClO4)2>Fe (ClO4)2.",

keywords = "Alkane hydroxylation, Biomimetic, Catalysis, m-chloroperbenzoic acid, Metal perchlorate, Monooxygenases",

author = "Wonwoo Nam and Ryu, \{Ju Yeon\} and Inwoo Kim and Cheal Kim",

year = "2002",

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journal = "Tetrahedron Letters",

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T1 - Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid

AU - Nam, Wonwoo

AU - Ryu, Ju Yeon

AU - Kim, Inwoo

AU - Kim, Cheal

PY - 2002/7/29

Y1 - 2002/7/29

N2 - Simple metal (M=Mn, Fe, Co) perchlorates associated with m-chloroperbenzoic acid are able to conduct stereoselective alkane hydroxylations via a mechanism involving metal-based oxidants; the catalytic activity of the metal salts is in the order of Co(ClO4)2>Mn(ClO4)2>Fe (ClO4)2.

AB - Simple metal (M=Mn, Fe, Co) perchlorates associated with m-chloroperbenzoic acid are able to conduct stereoselective alkane hydroxylations via a mechanism involving metal-based oxidants; the catalytic activity of the metal salts is in the order of Co(ClO4)2>Mn(ClO4)2>Fe (ClO4)2.

KW - Alkane hydroxylation

KW - Biomimetic

KW - Catalysis

KW - m-chloroperbenzoic acid

KW - Metal perchlorate

KW - Monooxygenases

UR - https://www.scopus.com/pages/publications/0037194185

U2 - 10.1016/S0040-4039(02)01060-2

DO - 10.1016/S0040-4039(02)01060-2

M3 - Article

AN - SCOPUS:0037194185

SN - 0040-4039

VL - 43

SP - 5487

EP - 5490

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid

Abstract

Keywords

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