Synthesis of novel tin complexes using functionalized oxime ligands

Eun Ae Jung; Sheby Mary George; Seong Ho Han; Bo Keun Park; Jeong Hwan Han; Seung Uk Son; Chang Gyoun Kim; Taek Mo Chung

doi:10.1016/j.ica.2016.02.056

Synthesis of novel tin complexes using functionalized oxime ligands

Eun Ae Jung, Sheby Mary George, Seong Ho Han, Bo Keun Park, Jeong Hwan Han, Seung Uk Son, Chang Gyoun Kim, Taek Mo Chung

Dept. of Materials Science & Engineering

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L¹)₂]₂ (1) and [Sn(L²)₂]₂ (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ₂-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.

Original language	English
Pages (from-to)	1-5
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	446
DOIs	https://doi.org/10.1016/j.ica.2016.02.056
State	Published - 1 May 2016

Keywords

Oxime
Precursor
Thin film
Tin

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10.1016/j.ica.2016.02.056

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title = "Synthesis of novel tin complexes using functionalized oxime ligands",

abstract = "Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L1)2]2 (1) and [Sn(L2)2]2 (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ2-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.",

keywords = "Oxime, Precursor, Thin film, Tin",

author = "Jung, \{Eun Ae\} and George, \{Sheby Mary\} and Han, \{Seong Ho\} and Park, \{Bo Keun\} and Han, \{Jeong Hwan\} and Son, \{Seung Uk\} and Kim, \{Chang Gyoun\} and Chung, \{Taek Mo\}",

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doi = "10.1016/j.ica.2016.02.056",

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T1 - Synthesis of novel tin complexes using functionalized oxime ligands

AU - Jung, Eun Ae

AU - George, Sheby Mary

AU - Han, Seong Ho

AU - Park, Bo Keun

AU - Han, Jeong Hwan

AU - Son, Seung Uk

AU - Kim, Chang Gyoun

AU - Chung, Taek Mo

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L1)2]2 (1) and [Sn(L2)2]2 (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ2-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.

AB - Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L1)2]2 (1) and [Sn(L2)2]2 (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ2-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.

KW - Oxime

KW - Precursor

KW - Thin film

KW - Tin

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DO - 10.1016/j.ica.2016.02.056

M3 - Article

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SN - 0020-1693

VL - 446

SP - 1

EP - 5

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Synthesis of novel tin complexes using functionalized oxime ligands

Abstract

Keywords

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