Synthesis of novel tin complexes using functionalized oxime ligands

Eun Ae Jung; Sheby Mary George; Seong Ho Han; Bo Keun Park; Jeong Hwan Han; Seung Uk Son; Chang Gyoun Kim; Taek Mo Chung

doi:10.1016/j.ica.2016.02.056

Synthesis of novel tin complexes using functionalized oxime ligands

Eun Ae Jung
, Sheby Mary George
, Seong Ho Han
, Bo Keun Park
, Jeong Hwan Han
, Seung Uk Son
, Chang Gyoun Kim
, Taek Mo Chung

Dept. of Materials Science & Engineering

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L¹)₂]₂ (1) and [Sn(L²)₂]₂ (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ₂-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.

Original language	English
Pages (from-to)	1-5
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	446
DOIs	https://doi.org/10.1016/j.ica.2016.02.056
State	Published - 1 May 2016

Keywords

Oxime
Precursor
Thin film
Tin

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10.1016/j.ica.2016.02.056

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title = "Synthesis of novel tin complexes using functionalized oxime ligands",

abstract = "Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L1)2]2 (1) and [Sn(L2)2]2 (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ2-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.",

keywords = "Oxime, Precursor, Thin film, Tin",

author = "Jung, \{Eun Ae\} and George, \{Sheby Mary\} and Han, \{Seong Ho\} and Park, \{Bo Keun\} and Han, \{Jeong Hwan\} and Son, \{Seung Uk\} and Kim, \{Chang Gyoun\} and Chung, \{Taek Mo\}",

year = "2016",

month = may,

day = "1",

doi = "10.1016/j.ica.2016.02.056",

language = "English",

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journal = "Inorganica Chimica Acta",

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T1 - Synthesis of novel tin complexes using functionalized oxime ligands

AU - Jung, Eun Ae

AU - George, Sheby Mary

AU - Han, Seong Ho

AU - Park, Bo Keun

AU - Han, Jeong Hwan

AU - Son, Seung Uk

AU - Kim, Chang Gyoun

AU - Chung, Taek Mo

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L1)2]2 (1) and [Sn(L2)2]2 (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ2-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.

AB - Novel tin complexes stabilized by alkoxy-functionalized oxime ligands [Sn(L1)2]2 (1) and [Sn(L2)2]2 (2), were prepared and characterized. Single-crystal X-ray diffraction analysis revealed that the complexes were obtained as dimers in which the tin metal centers are bridged by a pair of μ2-oxygen atoms. Due to the ligand steric effects, the metal centers in these complexes adopted an unusual distorted square pyramidal geometry and displayed interesting structural features. The thermo-gravimetric analyses of the complexes showed major mass loss in the 175-380°C region.

KW - Oxime

KW - Precursor

KW - Thin film

KW - Tin

UR - https://www.scopus.com/pages/publications/84960407977

U2 - 10.1016/j.ica.2016.02.056

DO - 10.1016/j.ica.2016.02.056

M3 - Article

AN - SCOPUS:84960407977

SN - 0020-1693

VL - 446

SP - 1

EP - 5

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Synthesis of novel tin complexes using functionalized oxime ligands

Abstract

Keywords

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