Synthesis of size-controlled CdSe quantum dots and characterization of CdSe-conjugated polymer blends for hybrid solar cells

Sang Hyun Choi, Hongju Song, Il Kyu Park, Jun Ho Yum, Seok Soon Kim, Seonghoon Lee, Yung Eun Sung

Research output: Contribution to journalArticlepeer-review

87 Scopus citations

Abstract

High-quality CdSe quantum dots (Qdots) were produced using the wet chemical synthetic method. These size-controlled CdSe Qdots were characterized by UV-vis absorption spectroscopy, photoluminescence (PL) spectroscopy, Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The XRD patterns and TEM images showed that the CdSe Qdots had a wurtzite crystalline structure. Bandgap-tuning CdSe Qdots were used to fabricate solar cells. We report the extensive experimental results of the CdSe Qdots-conjugated polymer composites used for the fabrication of the hybrid solar cells, by blending them between CdSe Qdots-poly (3-hexylthiophene) (P3HT) and CdSe Qdots/ [poly(1-methoxy-4-(2-ethylhexyloxy-2,5-phenylenevinylene))] (MEH-PPV) polymer.

Original languageEnglish
Pages (from-to)135-141
Number of pages7
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume179
Issue number1-2
DOIs
StatePublished - 1 Apr 2006

Keywords

  • CdSe quantum dots (Qdots)
  • Conjugated polymer
  • Hybrid solar cells

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