Tetra-μ-benzoato-bis-{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}

Seung Man Yu; Kyosang Koo; Pan Gi Kim; Cheal Kim; Youngmee Kim

doi:10.1107/S1600536809052714

Tetra-μ-benzoato-bis-{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}

Seung Man Yu, Kyosang Koo, Pan Gi Kim, Cheal Kim, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The central part of the title centrosymmetric dinuclear complex, [Zn ₂(C₇H₅O₂)₄(C ₉H₁₂N₂)₂], has a paddle-wheel conformation with four benzoate ligands bridging two symmetry-related Zn ^II ions. The distorted square-pyramidal coordination environment around the Zn^II ion is completed by an N atom from a 4-(pyrrolidin-1-yl)pyridine ligand. The Zn⋯Zn separation of 2.9826 (12) Å does not represent a formal direct metal-metal bond. The Zn^II ion is displaced by 0.381 (1) Å from the mean plane of the four basal O atoms. Two of the C atoms of the pyrrolidine ring are disordered over two sites with refined occupancies of 0.53 (2) and 0.47 (2).

Original language	English
Pages (from-to)	m61-m62
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	1
DOIs	https://doi.org/10.1107/S1600536809052714
State	Published - 2010

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title = "Tetra-μ-benzoato-bis-\{[4-(pyrrolidin-1-yl)pyridine]zinc(II)\}",

abstract = "The central part of the title centrosymmetric dinuclear complex, [Zn 2(C7H5O2)4(C 9H12N2)2], has a paddle-wheel conformation with four benzoate ligands bridging two symmetry-related Zn II ions. The distorted square-pyramidal coordination environment around the ZnII ion is completed by an N atom from a 4-(pyrrolidin-1-yl)pyridine ligand. The Zn⋯Zn separation of 2.9826 (12) {\AA} does not represent a formal direct metal-metal bond. The ZnII ion is displaced by 0.381 (1) {\AA} from the mean plane of the four basal O atoms. Two of the C atoms of the pyrrolidine ring are disordered over two sites with refined occupancies of 0.53 (2) and 0.47 (2).",

author = "Yu, \{Seung Man\} and Kyosang Koo and Kim, \{Pan Gi\} and Cheal Kim and Youngmee Kim",

year = "2010",

doi = "10.1107/S1600536809052714",

language = "English",

volume = "66",

pages = "m61--m62",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "1",

}

TY - JOUR

T1 - Tetra-μ-benzoato-bis-{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}

AU - Yu, Seung Man

AU - Koo, Kyosang

AU - Kim, Pan Gi

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2010

Y1 - 2010

N2 - The central part of the title centrosymmetric dinuclear complex, [Zn 2(C7H5O2)4(C 9H12N2)2], has a paddle-wheel conformation with four benzoate ligands bridging two symmetry-related Zn II ions. The distorted square-pyramidal coordination environment around the ZnII ion is completed by an N atom from a 4-(pyrrolidin-1-yl)pyridine ligand. The Zn⋯Zn separation of 2.9826 (12) Å does not represent a formal direct metal-metal bond. The ZnII ion is displaced by 0.381 (1) Å from the mean plane of the four basal O atoms. Two of the C atoms of the pyrrolidine ring are disordered over two sites with refined occupancies of 0.53 (2) and 0.47 (2).

AB - The central part of the title centrosymmetric dinuclear complex, [Zn 2(C7H5O2)4(C 9H12N2)2], has a paddle-wheel conformation with four benzoate ligands bridging two symmetry-related Zn II ions. The distorted square-pyramidal coordination environment around the ZnII ion is completed by an N atom from a 4-(pyrrolidin-1-yl)pyridine ligand. The Zn⋯Zn separation of 2.9826 (12) Å does not represent a formal direct metal-metal bond. The ZnII ion is displaced by 0.381 (1) Å from the mean plane of the four basal O atoms. Two of the C atoms of the pyrrolidine ring are disordered over two sites with refined occupancies of 0.53 (2) and 0.47 (2).

UR - https://www.scopus.com/pages/publications/74349106295

U2 - 10.1107/S1600536809052714

DO - 10.1107/S1600536809052714

M3 - Article

AN - SCOPUS:74349106295

SN - 1600-5368

VL - 66

SP - m61-m62

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

Tetra-μ-benzoato-bis-{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}

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