Tetra -μ-benzoatobis-{[trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene] zinc(II)}

Young Joo Song; Soo Won Lee; Kyung Hwan Jang; Cheal Kim; Youngmee Kim

doi:10.1107/S1600536809045048

Tetra -μ-benzoatobis-{[trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene] zinc(II)}

Young Joo Song, Soo Won Lee, Kyung Hwan Jang, Cheal Kim, Youngmee Kim

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The paddle-wheel-type centrosymmetric dinuclear title complex, [Zn2(C ₇H₅O₂)4(C₁₂H₁₀N ₂)2], contains four bridging benzoate groups and two terminal trans-1-(2-pyrid-yl)-2-(4-pyrid-yl)ethyl-ene (L) ligands. The inversion center is located between the two Zn^II atoms. The octa-hedral coordination around the Zn^II atom, with four O atoms in the equatorial plane, is completed by an N atom of the L mol-ecule [Zn - N = 2.0198 (15) Å] and by the second Zn^II atom [Zn⋯Zn = 2.971 (8) Å]. The Zn ^II atom is 0.372 Å out of the plane of the four coordinating O atoms.

Original language	English
Pages (from-to)	m1495-m1496
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	12
DOIs	https://doi.org/10.1107/S1600536809045048
State	Published - 2009

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title = "Tetra -μ-benzoatobis-\{[trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene] zinc(II)\}",

abstract = "The paddle-wheel-type centrosymmetric dinuclear title complex, [Zn2(C 7H5O2)4(C12H10N 2)2], contains four bridging benzoate groups and two terminal trans-1-(2-pyrid-yl)-2-(4-pyrid-yl)ethyl-ene (L) ligands. The inversion center is located between the two ZnII atoms. The octa-hedral coordination around the ZnII atom, with four O atoms in the equatorial plane, is completed by an N atom of the L mol-ecule [Zn - N = 2.0198 (15) {\AA}] and by the second ZnII atom [Zn⋯Zn = 2.971 (8) {\AA}]. The Zn II atom is 0.372 {\AA} out of the plane of the four coordinating O atoms.",

author = "Song, \{Young Joo\} and Lee, \{Soo Won\} and Jang, \{Kyung Hwan\} and Cheal Kim and Youngmee Kim",

year = "2009",

doi = "10.1107/S1600536809045048",

language = "English",

volume = "65",

pages = "m1495--m1496",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

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TY - JOUR

T1 - Tetra -μ-benzoatobis-{[trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene] zinc(II)}

AU - Song, Young Joo

AU - Lee, Soo Won

AU - Jang, Kyung Hwan

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2009

Y1 - 2009

N2 - The paddle-wheel-type centrosymmetric dinuclear title complex, [Zn2(C 7H5O2)4(C12H10N 2)2], contains four bridging benzoate groups and two terminal trans-1-(2-pyrid-yl)-2-(4-pyrid-yl)ethyl-ene (L) ligands. The inversion center is located between the two ZnII atoms. The octa-hedral coordination around the ZnII atom, with four O atoms in the equatorial plane, is completed by an N atom of the L mol-ecule [Zn - N = 2.0198 (15) Å] and by the second ZnII atom [Zn⋯Zn = 2.971 (8) Å]. The Zn II atom is 0.372 Å out of the plane of the four coordinating O atoms.

AB - The paddle-wheel-type centrosymmetric dinuclear title complex, [Zn2(C 7H5O2)4(C12H10N 2)2], contains four bridging benzoate groups and two terminal trans-1-(2-pyrid-yl)-2-(4-pyrid-yl)ethyl-ene (L) ligands. The inversion center is located between the two ZnII atoms. The octa-hedral coordination around the ZnII atom, with four O atoms in the equatorial plane, is completed by an N atom of the L mol-ecule [Zn - N = 2.0198 (15) Å] and by the second ZnII atom [Zn⋯Zn = 2.971 (8) Å]. The Zn II atom is 0.372 Å out of the plane of the four coordinating O atoms.

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U2 - 10.1107/S1600536809045048

DO - 10.1107/S1600536809045048

M3 - Article

AN - SCOPUS:72049090921

SN - 1600-5368

VL - 65

SP - m1495-m1496

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Tetra -μ-benzoatobis-{[trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene] zinc(II)}

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