The two-dimensional structure of poly[[diperchloratocopper(II)]- bis[μ2-1,3-bis(4-pyridyl)propane]]

Ji Young Ryu, Cheal Kim, Dae Won Park, Lae Ok Park, Youngmee Kim, Alan J. Lough

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Abstract

In the crystal structure of the title compound, [Cu(ClO4) 2(C13H14N2)2] n there are two independent CuII ions, one of which occupies a crystallographic inversion center. The 1,3-bis(4-pyridyl)propane ligands bridge the CuII ions to form two independent two-dimensional sheets. In addition, two terminal perchlorate anions are coordinated to each CuII ion, resulting in distorted octahedral coordination around each CuII ion. The equatorial Cu-N bonds are in the range 2.014 (4)-2.031 (4) Å, while the long axial Cu-O distances range from 2.434 (3) to 2.548 (3) Å.

Original languageEnglish
Pages (from-to)m1489-m1491
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number8
DOIs
StatePublished - 1 Aug 2005

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