The two-dimensional structure of poly[[diperchloratocopper(II)]- bis[μ2-1,3-bis(4-pyridyl)propane]]

Ji Young Ryu; Cheal Kim; Dae Won Park; Lae Ok Park; Youngmee Kim; Alan J. Lough

doi:10.1107/S1600536805020878

The two-dimensional structure of poly[[diperchloratocopper(II)]- bis[μ₂-1,3-bis(4-pyridyl)propane]]

Ji Young Ryu
, Cheal Kim
, Dae Won Park
, Lae Ok Park
, Youngmee Kim
, Alan J. Lough

Dept. of Fine Chemistry

Seoul National University of Science and Technology (SNUST)
646-9 BH Biomedic Company
Ewha Womans University
University of Toronto

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

In the crystal structure of the title compound, [Cu(ClO₄) ₂(C₁₃H₁₄N₂)₂] _n there are two independent Cu^II ions, one of which occupies a crystallographic inversion center. The 1,3-bis(4-pyridyl)propane ligands bridge the Cu^II ions to form two independent two-dimensional sheets. In addition, two terminal perchlorate anions are coordinated to each Cu^II ion, resulting in distorted octahedral coordination around each Cu^II ion. The equatorial Cu-N bonds are in the range 2.014 (4)-2.031 (4) Å, while the long axial Cu-O distances range from 2.434 (3) to 2.548 (3) Å.

Original language	English
Pages (from-to)	m1489-m1491
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	8
DOIs	https://doi.org/10.1107/S1600536805020878
State	Published - 1 Aug 2005

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title = "The two-dimensional structure of poly[[diperchloratocopper(II)]- bis[μ2-1,3-bis(4-pyridyl)propane]]",

abstract = "In the crystal structure of the title compound, [Cu(ClO4) 2(C13H14N2)2] n there are two independent CuII ions, one of which occupies a crystallographic inversion center. The 1,3-bis(4-pyridyl)propane ligands bridge the CuII ions to form two independent two-dimensional sheets. In addition, two terminal perchlorate anions are coordinated to each CuII ion, resulting in distorted octahedral coordination around each CuII ion. The equatorial Cu-N bonds are in the range 2.014 (4)-2.031 (4) {\AA}, while the long axial Cu-O distances range from 2.434 (3) to 2.548 (3) {\AA}.",

author = "Ryu, \{Ji Young\} and Cheal Kim and Park, \{Dae Won\} and Park, \{Lae Ok\} and Youngmee Kim and Lough, \{Alan J.\}",

year = "2005",

month = aug,

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doi = "10.1107/S1600536805020878",

language = "English",

volume = "61",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - The two-dimensional structure of poly[[diperchloratocopper(II)]- bis[μ2-1,3-bis(4-pyridyl)propane]]

AU - Ryu, Ji Young

AU - Kim, Cheal

AU - Park, Dae Won

AU - Park, Lae Ok

AU - Kim, Youngmee

AU - Lough, Alan J.

PY - 2005/8/1

Y1 - 2005/8/1

N2 - In the crystal structure of the title compound, [Cu(ClO4) 2(C13H14N2)2] n there are two independent CuII ions, one of which occupies a crystallographic inversion center. The 1,3-bis(4-pyridyl)propane ligands bridge the CuII ions to form two independent two-dimensional sheets. In addition, two terminal perchlorate anions are coordinated to each CuII ion, resulting in distorted octahedral coordination around each CuII ion. The equatorial Cu-N bonds are in the range 2.014 (4)-2.031 (4) Å, while the long axial Cu-O distances range from 2.434 (3) to 2.548 (3) Å.

AB - In the crystal structure of the title compound, [Cu(ClO4) 2(C13H14N2)2] n there are two independent CuII ions, one of which occupies a crystallographic inversion center. The 1,3-bis(4-pyridyl)propane ligands bridge the CuII ions to form two independent two-dimensional sheets. In addition, two terminal perchlorate anions are coordinated to each CuII ion, resulting in distorted octahedral coordination around each CuII ion. The equatorial Cu-N bonds are in the range 2.014 (4)-2.031 (4) Å, while the long axial Cu-O distances range from 2.434 (3) to 2.548 (3) Å.

UR - https://www.scopus.com/pages/publications/32244435075

U2 - 10.1107/S1600536805020878

DO - 10.1107/S1600536805020878

M3 - Article

AN - SCOPUS:32244435075

SN - 1600-5368

VL - 61

SP - m1489-m1491

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

The two-dimensional structure of poly[[diperchloratocopper(II)]- bis[μ₂-1,3-bis(4-pyridyl)propane]]

Abstract

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