Three-dimensional zinc(II) and cadmium(II) coordination frameworks with N, N, N ′, N ′-tetrakis(pyridin-4-yl)methanediamine: Structure, photoluminescence, and catalysis

Jong Won Shin; Jeong Mi Bae; Cheal Kim; Kil Sik Min

doi:10.1021/ic302375z

Three-dimensional zinc(II) and cadmium(II) coordination frameworks with N, N, N ′, N ′-tetrakis(pyridin-4-yl)methanediamine: Structure, photoluminescence, and catalysis

Jong Won Shin, Jeong Mi Bae, Cheal Kim, Kil Sik Min

Dept. of Fine Chemistry

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

Coordination polymer networks, i.e., [Zn(tpmd)(H₂O)](NO ₃)₂·7H₂O (1) and [Cd(tpmd)(H ₂O)₂](NO₃)₂·4H ₂O·4CH₃OH (2), were assembled from M ^II(NO₃)₂ hydrates (M = Zn, Cd) and N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd) in CH ₃OH and characterized. 1 and 2 feature three-dimensional networks formed by coordination of the metal ions to the tpmd ligands. 1 exhibits a strong blue emission at ∼397 nm, while 2 shows strong emission at ∼361 nm. 1 is a more efficient catalyst for the transesterification of various esters than 2.

Original language	English
Pages (from-to)	2265-2267
Number of pages	3
Journal	Inorganic Chemistry
Volume	52
Issue number	5
DOIs	https://doi.org/10.1021/ic302375z
State	Published - 4 Mar 2013

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title = "Three-dimensional zinc(II) and cadmium(II) coordination frameworks with N, N, N ′, N ′-tetrakis(pyridin-4-yl)methanediamine: Structure, photoluminescence, and catalysis",

abstract = "Coordination polymer networks, i.e., [Zn(tpmd)(H2O)](NO 3)2·7H2O (1) and [Cd(tpmd)(H 2O)2](NO3)2·4H 2O·4CH3OH (2), were assembled from M II(NO3)2 hydrates (M = Zn, Cd) and N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd) in CH 3OH and characterized. 1 and 2 feature three-dimensional networks formed by coordination of the metal ions to the tpmd ligands. 1 exhibits a strong blue emission at ∼397 nm, while 2 shows strong emission at ∼361 nm. 1 is a more efficient catalyst for the transesterification of various esters than 2.",

author = "Shin, {Jong Won} and Bae, {Jeong Mi} and Cheal Kim and Min, {Kil Sik}",

year = "2013",

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T1 - Three-dimensional zinc(II) and cadmium(II) coordination frameworks with N, N, N ′, N ′-tetrakis(pyridin-4-yl)methanediamine

T2 - Structure, photoluminescence, and catalysis

AU - Shin, Jong Won

AU - Bae, Jeong Mi

AU - Kim, Cheal

AU - Min, Kil Sik

PY - 2013/3/4

Y1 - 2013/3/4

N2 - Coordination polymer networks, i.e., [Zn(tpmd)(H2O)](NO 3)2·7H2O (1) and [Cd(tpmd)(H 2O)2](NO3)2·4H 2O·4CH3OH (2), were assembled from M II(NO3)2 hydrates (M = Zn, Cd) and N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd) in CH 3OH and characterized. 1 and 2 feature three-dimensional networks formed by coordination of the metal ions to the tpmd ligands. 1 exhibits a strong blue emission at ∼397 nm, while 2 shows strong emission at ∼361 nm. 1 is a more efficient catalyst for the transesterification of various esters than 2.

AB - Coordination polymer networks, i.e., [Zn(tpmd)(H2O)](NO 3)2·7H2O (1) and [Cd(tpmd)(H 2O)2](NO3)2·4H 2O·4CH3OH (2), were assembled from M II(NO3)2 hydrates (M = Zn, Cd) and N,N,N′,N′-tetrakis(pyridin-4-yl)methanediamine (tpmd) in CH 3OH and characterized. 1 and 2 feature three-dimensional networks formed by coordination of the metal ions to the tpmd ligands. 1 exhibits a strong blue emission at ∼397 nm, while 2 shows strong emission at ∼361 nm. 1 is a more efficient catalyst for the transesterification of various esters than 2.

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ER -

Three-dimensional zinc(II) and cadmium(II) coordination frameworks with N, N, N ′, N ′-tetrakis(pyridin-4-yl)methanediamine: Structure, photoluminescence, and catalysis

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